2010最新NMR中残留溶剂或者杂质的标准化学位移.pdfVIP

Organometallics XXXX, XXX, 000–000 A DOI: 10.1021/om100106e NMR Chemical Shifts of Trace Impurities: Common Laboratory Solvents, Organics, and Gases in Deuterated Solvents Relevant to the Organometallic Chemist Gregory R. Fulmer,*,† Alexander J. M. Miller,‡ Nathaniel H. Sherden,‡ Hugo E. Gottlieb,§ Abraham Nudelman,§ Brian M. Stoltz,‡ John E. Bercaw,‡ and Karen I. Goldberg† †Department of Chemistry, University of Washington, Box 351700, Seattle, Washington 98195-1700, ‡Arnold and Mabel Beckman Laboratories of Chemical Synthesis and Caltech Center for Catalysis and Chemical Synthesis, Division of Chemistry and Chemical Engineering, California Institute of Technology, Pasadena, California 91125, and §Department of Chemistry, Bar Ilan University, Ramat Gan 52900, Israel Received February 11, 2010 Tables of 1H and 13C NMR chemical shifts have been compiled for common organic compounds often used as reagents or found as products or contaminants in deuterated organic solvents. Building upon the work of Gottlieb, Kotlyar, and Nudelman in the Journal of Organic Chemistry, signals for common impurities are now reported in additional NMR solvents (tetrahydrofuran-d , toluene-d , 8 8 dichloromethane-d ,