多胺法(改良MDEA)脱除二氧化碳工艺.doc

多胺法(改良MDEA)脱除二氧化碳工艺 张学模 陆峰2 1.原南化集团研究院， 南京 210007 2. 江苏省常州市宇平化工有限公司 常州213169 摘要：该文叙述了多胺法（改良MDEA）脱除CO2的基本原理——MDEA与CO2的反应机理和MDEA对CO2具有物理吸收及化学吸收的双重性，以及本工艺的双活化剂的独特性。本文介绍了在合成氨及甲醇生产中采用本工艺脱CO2具有净化度高，能同时脱除硫化物，吸收能力高，热能耗低，溶液损失少，可利用闪蒸提高再生气CO2纯度等特点，以及在各种工况下的工艺流程和消耗指标。本文还叙述了本工艺近几年来的技术新进展,新装置的投运情况和利用本工艺的CO2再生气生产食品级CO2。最后文中叙述部分工厂生产误区造成的设备腐蚀、溶剂起泡，热能耗高，净化度差等问题以及解决办法。 关键词：多胺法；脱CO2工艺；净化；吸收；再生 Energy-Saving And Efficient Process for Removal of Carbon Dioxide— Multi-Amine Method (Improved MDEA) And Its Application ZhangXueMo1 LuFen2 1.The Fromer Research Institute of Nanjing Chemical Group,Nanjing 21007 2.Jiangsu Province Changzhou YiPing Chemical Limited Company,Changzhou 213169 Abstract: This paper describes the basic principle of Multi-Amine(Improved MDEA) Process for Removal of Carbon Dioxide——the reaction mechanism of MDEA with Carbon Dioxide, and the solvent properties of both chemical and physical,and the peculiarity of the dual-active agents in this Process. This paper introduces the characteristics of Multi-Amine(Improved MDEA) Process in synthetic ammonia and methanol production,high CO2 purification efficiency, sulphide removing at the same time, high absorb ability,low energy comsumption,low solvent loss,improving resurgent gas CO2 purity by making use of flashing，as well as the process flow and comsume data under various conditions. It still describes the craft progress in recent years.It describes the using of the new installation and eatable Carbon Dioxide production by making use of by-product resurgent gas CO2 .At last it describes the mistake areas of parts of factories production such as equipments corrosion,solution foaming,high thermal energy consumption, the bad decontamination degree etc,and the solutions of those problems. Keyword：Multi-Amine method, Process for Removal of Carbon Dioxide ,decontamination, absorb, resurgent 1 概况 活化MDEA是20世纪70年代初西德巴斯夫(BASF)公司开发的一种以甲基二乙醇胺(MDEA)水溶液为基础的脱CO2新工艺，近30年来，这种溶剂系统已被成功地应用于许多工业装置。由于MDEA对CO2有特殊的溶解性，因而具有许多优点，工艺过程能耗低。