超声波辅助脱除渣油中的金属杂质.pdfVIP

学兔兔 石 油 化 工 · 52· PETR0CHEMICAL TECHN0L0GY 2010年第39卷第1期 超声波辅助脱除渣油中的金属杂质 陈菲菲，赵德智，于 洋，宋小梅，丁 巍 (辽宁石油化工大学 石油化工学院，辽宁 抚顺 113001) [摘要]在辽河渣油中加入金属脱除剂，借助超声波的辅助作用，脱除了渣油中金属杂质。考察了脱除剂种类、脱除剂用量、脱除 剂的pH、超声波辐射时间、超声波强度和超声波频率对金属脱除率的影响。实验结果表明，在超声波作用下，金属脱除率明显高 于未加超声波的金属脱除率；超声波辅助脱除渣油中金属杂质的适宜反应条件为：渣油用量60 g、水质量分数(相对于渣油)10％、 脱除剂用量2 000 p~g／g、超声波辐射时间25 min、超声波强度10 W／cm 、超声波频率28 kHz。在此条件下，加入pH为5．0的CNP (草酸氨、氟化氨和磷酸的混合溶液)脱除剂时，ca的脱除率为85．24％；加入pH为5．5的CNNF(草酸氨、氟化氨、柠檬酸和氟化 氢的混合溶液)脱除剂时，Ni脱除率为83．23％。 [关键词]超声波；渣油；脱除金属杂质；钙；镍 [文章编号]1000—8144(2010)O1—0052—05 [中图分类号]TE 624 [文献标识码]A Demetallization from Residual Oil Under Auxiliary Ultrasonic Radiation Chen Feifei，Zhao Dezhi，Yu Yang，Song Xiaomei，Ding Wei (Liaoning University of PetroleumChemical Technology，Fushun Liaoning 113001，China) [Abstract]The removal of metal impurity from Liaohe residual oil in the presence of demetalization agent under ultrasonic radiation was studied．The metallic contents in the residual oil before and after demetalization were analyzed by means of atomic absorption spectrophotometry． The effects of auxiliary ultrasonic radiation，demetalization agent type，ultrasonic radiation time，ultrasonic intensity and ultrasonic frequency on the removal of the metal impurity were discussed．The demetalization effect with ultrasonic radiation was much better than that without it．Under the suitable conditions： residual o订60 g，water mass fraction 10％(based on residual oil)，demetalization agent dosage 2 000 txg／g，ultrasonic radiation time 25 min，ultrasonic intensity 1 0 W／cm and ul