全取代环戊基六元瓜环晶体制备及其晶体结构研究.pdfVIP

人工晶体学报 第45 卷第 12 期 Vol. 45 No.12 2016 年 12 月 JOURNAL OF SYNTHETIC CRYSTALS December ,2016 全取代环戊基六元瓜环晶体制备及其晶体结构研究 张友禄，魏莉 (大连工业大学轻工与化学工程学院，大连 116034 ) 在稀盐酸条件下长的晶体进行 摘要:研究了对全取代环戊基六元瓜环(Cy因Q6)与结构诱导剂 ZnCl x-射线单晶 2 衍射分析。通过实验得到一个新的晶体，其结构表明，晶体属于斜方晶系，空间群为 P2 /n ， a = 27. 599 ( 7) Å,b = 1 17. 393 (7) Å , c = 18. 265 (5) Å ， α=90. ∞。 ， ß = 93. 369 ( 6 ) 0 ， γ=90. ∞。 ， Z =4 ,R =0.046 ，其中结构中出现了蜂巢 效应并且形成了较大的孔道。 关键词:全取代环戊基六元瓜环;x 射线单晶衍射;晶体结构 中图分类号:0741 文献标识码:A 文章编号:1 ∞0-985X( 2016) 12-2878-04 Synthesis and Crystal Structure of Cyclopentano Cucurbit [ 6 ]uril ZHANG You-lu , WEI Li (School of Light and Chemical Engineering , Dalian Polytechnic University , Dalian 116034 , China) Abstract: Carrying through X -ray single crystal diffraction analysis of the fully substituted Cyclopentano cucurbit [ 6 ] uril (CyP6Q6) and structure inducing agent of ZnCl2 in dilute hydrochloric acid under the condition of long crystal was mainly studied in this paper. A new crystal through the experiments were getted. The structure was showed that the crystal belongs to orthorhombic. The space group is P2 /n ， α=