由碳酸二甲酯合成异氰酸酯_史芸.pdf

() 2010 8 　 　　　 　　　ACTA PETRO LEI SINICA (PETRO LEUM P ROCESSING SECTION)　 　　 　　　26 4 　 :1001-8719(2010)04-0648-09 1 2 1 1 史　芸, 张广林 , 王胜平, 马新宾 (1. , 300072;2. , 300130) :, 。 (DMC), 。 、 、 , , 。(M DI)、 2, 4- (TDI)、1, 6-(HDI)。 　　:;;;2,4-;1, 6- :T 323.8 　　:A 　　doi:10.3969/j.issn.1001-8719.2010.04.028 SYNTHESIS OF ISOCYANATESFROM DIMETHYLCARBONATE 1 2 1 1 SHI Yun , ZHANG Guanglin , WANG Shengping , MA Xinbin (1.K ey L abora tory f or Green Chem ica l Technolog y of Mi nistry of E d ucat ion, S chool of Chemical En g i neer ing and Technolog y , Tianj in Uni versi ty , Tianj in 300072, Ch ina; 2.S chool of Chemica l Eng ineeri ng Technolo gy , H ebe i Uni versi ty of Technol ogy , T ianj i n 300130, Chi na) Abstract:Isocyanate, as an important organic intermediate, is the primary material of producing polyurethane.Utilizing dimethyl carbonate as the substitute of phosgene, the synthesis of isocyanate includes two steps, which are the methoxycarbonylation of amines with dimethyl carbonate to produce carbamates and the decomposition of carbamates to obtain isocyanate.Due to non-toxicity, non-pollution and high-atom economy, this method is a well promising route to synthesize isocyanate, which greatly accorded with the development trend of green chemical industry .In this paper the process research and technological progress of synthesis of several important isocyanates from dimethyl carbonate, such as methylene diphenyl diisocyanate, 2,4-toluene diisocyanate, 1,6-hexamethylene diisocyanate and so on are emphatically introduced. Key words:isocyanates;dimethyl carbonate;methylene diphenyl diis