Fe(Ⅲ)-EDDS体系紫外光降解橙黄Ⅱ.pdfVIP

第 3 5 卷第 3 期 中南民族大学学报（自然科学版） Vol.35 No. 3 2 0 1 6 年 9 月 Journal of South-Central University for Nationalities( Nat. Sci. Edition) Sep. 2016 Fe (皿）-：EDDS体系紫外光降解橙黄II 孙 杰 ，王 浪 ，张 晗 (中南民族大学资源与环境学院，武汉430074) 摘 要 研究了 Fe (n )-E D D s 体系在紫外光照射下对橙黄n 的光降解过程,对橙黄n 在不同条件下的降解过程 进行了动力学分析，使用响应面分析法（R S A )得出了较佳的降解条件，并考察了氧化性物种• 0H 和 Of •对橙黄 n 降解的影响.结果表明:U V /Fe ( m )-E D D S 体系能有效降解橙黄n ,紫外光条件下该体系能在p H 在 3 ~9范围内 对橙黄n 降解效果保持良好，橙黄n 在体系中的降解符合拟一级动力学反应规律.通过响应面分析得出了橙黄n 降解的最优条件为:pH=4.0,C[Fe(^)]=0.06mM,C(EDDS)=0.20mM.猝灭实验反应产生了•OH和02_•,其 中 • o h 为橙黄n 光降解主要的反应物种.反应前后f t -i r 图显示在光降解过程中，苯环发生开环，橙黄n 的结构被 破坏，生成小分子物质. 关键词 Fe ( n ) -E D D S 配合物;橙黄n ;光降解;响应面法;猝灭法 中图分类号 T Q 138.1 文献标识码 A 文章编号2016)03-0006-07 Degradation of Orange II by Fe(n)-EDDS Under Ultraviolet Irradiation Sun J i e , W ang L a n g, Z h a n g Han ( College of Resources and Environmental Science,South-Central University for Nationalities,Wuhan 4 3 0 0 7 4 ,China) Abstract Photo-degradation of Orange II was studied in the Fe ( IH ) -EDDS system under UV irradiation. The dependence of photochemical bleaching kinetics of Orange II was investigated under different conditions, and the favorable degradation condition was obtained by using response surface analysis ( R S A ) . The results showed that the Fe( IH ) -EDDS system was effective for the degradation of Orange I I ， which occurred in the pH range of 3 〜 9 and followed pseudo-first order kinetics. The optimal degradation conditions obtained by using RSA was as follows ：pH = 4 ， c [ Fe ( IH ) ] = 0. 06