烃类化合物气相色谱保留指数与其分配系数关系研究-环境科学学报.PDF

21 5 Vol. 21, No. 5 2001 9 ACTA SCIENT IAE CIRCUMSTANTIAE Sep. , 2001 : 200 1 : X132, O 623 : A 朱秀华, 王 炜 ( , 116028) : , , , . : ; ; The relationship between partition coefficients of hydrocarbons and their retention indices ZHU Xiuhua, WANG Wei ( Depar men of Environmen al Science and Engineering, Dalian Railway Ins i u e, Dalian 116028) Abstract: Using he re en ion indices of hydrocarbons o predic he oc anolwa er par i ion coeff icien s( logK ow ) is proposed. The influence of he polariy of he s a ionary phase on he degree of accuracy of he predic ing value of he logK ow was s udied. The re en ion indices ha de er mined on he weak polar s a ionary phase can give more accura e predic ing value of he logK ow. The hydrocarbon should be classified as paraf fin, olefins, naph henes and aroma ics, hen he ideal resul can be go en by each ype of predic ing formula. Keywords: re en ion index; hydrocarbon; oc anolwa er par i ion coeff icien s , , [ 1] [ 2] . , ( I ) , [ 1] ( logK ow ) , , , . 1 [ 3] , , , . , , 12 , , Squalane, OV101, SE30 PEG20M [ 2] , DB1, DB5 [ 4 , 5] , Apiezon L, Ucon LB550X, Ucon 50HB280X, Carbow ax 20M , Carbow ax 1540, TCEP [ 6] , [ 1] . , , , , ( I ) ( logK ow ) . : : 200 10120 : ( 99292 1696) : ( 1965 ) , , ( ) 632 21 : logK ow = a + b lnI ( 1) : I ; K ow ; a , b . 1 OV101 logK ow . 1 T able 1 The re en ion indices and par i ion