[U（CO3）3（H2O）2]·2H2O配合物的合成及晶体结构.pdfVIP

第 26卷第 2期 无 机 化 学 学 报 V01．26No．2 2010年 2月 CHINESEJOURNALOFIN0RGANICCHEMISTRY 351—354 [U(CO3)3(H20)2]·2H2O配合物的合成及晶体结构 王 娟 ，I 吕 鑫 李子颖2 张玉燕 2 程时远 1 f湖北大学化学化工学院，武汉 4300621 2X_z-部北京地质研 究院，北京 100029) 关键词 ：铀 ；晶体结构 ：碳酸根 中图分类号：0614．62 文献标识码：A 文章编号：1001-461(2010)020351．04 SynthesisandCrystalStructureofaUranylc0ntainingComplex U【(CO3)3(H2o)2]·2H20 WANGJuan L0Xin LIZi．Ying ZHANGYu—Yan CHENGShi．Yuan (SchoolofChemistryandChemicalEngineering,HubeiUniversity,Wuhna430062) (2BeijingResearchInsitituteofUraniumGeology,Bering100029) Abstract：Auranylc0ntainingcompoundu【(co3)3(H20)2]·2H20hasbeensynthesizedunderhydrothermalcondition andcharacterizedbyX—raysingle—crystalanalysis．Crystalstructuralanalysisindicatesthatthiscompoundconsists ofthreeCO3 molecules，oneU ．Theresultsrevealthatthetitlecompoundpresentsa3D frameworkbuiltupbyO～ H … O weekhydrogenbondsinteractions．Thecentraluranium atom iseight—coordinatedthrough threeCO3一 moleculesandtwoH20．Thecompoundshowsacoplanarhexagonalnetworksturcture，eachhexagoncontaininga hexagonalholewithawatermoleculet．CCDC：737313． Keywords：uranium；crystalstructure；carbonate Uranium(、7Disacommonactinideofundinnatural lexeswithC032一toform verysolublespecies，which mediaand inradioactivewaste．Moreover，itisoften significantly inhibitsadsorptionofU ontosurfacesof takenasamodelforotheractinidesfound inradioa． solidssuch asamoprhousFe—Mn oxides，claysand ctivewaste．Thegeochemistry ofuranium inoceansiS organicparticles．Thisisconsistentwiththeabsenceof mainlycharacterizedby (1)reduction．oxidationreac． anyverticalUconcentration，[U】，variationsMongthe tions changing U between two dominantoxidation