热处理气氛对硷化处理Ti-6Al-4V表面性质之影响.doc

熱處理氣氛對鹼化處理Ti-6Al-4V表面性質之影響 The effects of heat treatment atmosphere conditions on the alkali-modified Ti-6Al-4V surface properties 研究生：黃信銘 Huang, Hsin-Ming 指導教授：洪廷甫 Honng, Ting-Fu 【摘要】 本研究主要探討經5 M、10 M NaOH鹼化處理與去離子水處理後之Ti-6Al-4V試片分別經由600°C大氣及真空熱處理條件下，所形成鈦酸鈉水凝膠層並分別進行結晶相結構、表面形貌、成份分析、表面粗糙度、親疏水性及機械性質等分析，並浸泡於人工模擬體液(Simulated Body Fluid, SBF)，來觀察鈦合金試片表面形成類骨質層之差異性。本研究所使用人工模擬體液為(Modified SBF, m-SBF)，浸泡時間為1~28天5 M、10 M 鹼化處理皆可將鈦合金試件表面生物活性化，經由大氣熱處理後皆有效提升鈦酸鈉水凝膠層與基材之附著強度、彈性係數等機械性質。5 M、10 M NaOH鹼化去離子水處理後於600°C大氣及真空熱處理，並浸泡於m-SBF中皆可在第5天內生成類骨質層。NaOH鹼熱處理後並浸泡於m-SBF 1~28天，進行奈米壓痕試驗由實驗結果可得到，大氣熱處理能提高試片表面被覆層之機械性質，但真空熱處理後試片表面因缺乏氧原子擴散反The purpose of this study is to investigate the bone-like apatite inducement ability on the 5, 10 NaOH, deionized water (D.I. water) and 600°C atmospheric and the vacuum heat treated Ti-6Al-4V surfaces. All the generated sodium titanate surfaces of samples were characterized their crystallographic structure, morphology, chemical composition, surface roughness, contact angle measurement and mechanical properties, respectively. Ti-6Al-4V surfaces in the simulated body fluid (SBF) solutions, monitoring the mobility changes of the bone-like apatite layer formation process on Ti-6Al-4V specimen surfaces. The treated specimens were soaked in m-SBF for 1~28 days for bioactivity evaluation. The results showed that 5M and 10M alkali treatments can successfully bioactivate the Ti-6Al-4V specimen surfaces. The specimen with following heat treatment at 600?C even had crystallinity intensity of generated sodium titanate and elastic constants. After soaking in the m-SBF, a thin bone-like apatite layer was formed along the heat treated Ti-6Al-4V surfaces with in 5 days. The treated specimens followed by NaOH were soaked in m-SBF for 1~28 days for Nano-indentation test. The experimental results show that specimen surfaces mechanical properties are promoted when atmospheric treated. However, the surface after vacuum heat treatment due to lack of TiO2, the mechanical propert