电子浆料用纳米Ag粉的制备及表面处理.pdf

第28 卷 第6 期 电 子 元 件 与 材 料 Vol.28 No.6 2009 年6 月 ELECTRONIC COMPONENTS AND MATERIALS Jun. 2009 研 究 与 试 制 电子浆料用纳米Ag 粉的制备及表面处理 唐元勋，孟淑媛，吴海斌 （广东风华高新科技股份有限公司，广东 肇庆 526020） 摘要: 以有机酸为分散剂，三乙醇胺为还原剂，采用高温化学还原法制备纳米 Ag 粉，并对粉体进行表面处理。 研究了 Ag O 粉比表面积、还原剂添加量、反应温度、表面处理及干燥温度等对 Ag 粉性能的影响。在醇类溶剂中 2 于(88 ± 2) ℃还原比表面积大于 3.000 m2/g 的Ag O 粉，制备了黑色纳米 Ag 粉，其粒径为 50 ~ 150 nm ，比表面积大 2 于 8.000 m2 3 /g ，振实密度高于2.5 g/cm 。用液体树脂对Ag 粉进行表面处理拓宽了粉体干燥温度，能有效阻止团聚 和自烧结的发生，提高粉体分散性。 关键词: 电子浆料；纳米Ag 粉；表面处理；液体树脂 doi: 10.3969/j.issn.1001-2028.2009.06.005 中图分类号: TB383 文献标识码:A 文章编号:1001-2028 （2009 ）06-0016-03 Preparation and surface treatment of silver nanopowder used in electronic paste TANG Yuanxun, MENG Shuyuan, WU Haibin (Guangdong Fenghua Advanced Technology Holding Co., Ltd, Zhaoqing 526020, Guangdong Province, China) Abstract: Ag nanopowder with surface treatment was prepared by chemical reduction at high temperature using triethanolamine as reducer and organic acid as dispersant. The effects of specific surface areas of Ag2O powder, reducer additive amounts, reaction temperatures，surface treatment and drying temperatures on the properties of Ag nanopowder 2 were studied. Ag2O powder with special surface area of more than 3.000 m /g was reduced to black Ag nanopowder in alcoholic solvents at (88 ± 2)℃.The black Ag nanopowder has a particle size of 50~150 nm, a special surface are