《Poly（benzoxazine）s Modified with Osmium Complexes as a Class of Redox Polymers for Wiring of Enzymes to Electrode Surfaces》.pptxVIP

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2017-06-01 发布于浙江
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《Poly（benzoxazine）s Modified with Osmium Complexes as a Class of Redox Polymers for Wiring of Enzymes to Electrode Surfaces》.pptx

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Poly(benzoxazine)s Modified with Osmium Complexes as a Class of Redox Polymers for Wiring of Enzymes to Electrode Surfaces;Company Logo; The Os complexes are redox active within he polymer films, and thus, can be used as redox relays for the electron transfer between the electrode surface and the prosthetic group within the enzyme. Entrapment of GOx within the poly(benzoxazine) film is achieved successfully, as shown by the biocatalytic activity of the poly(benzoxazine)/GOx films upon the addition of glucose.; Introduction Poly(benzoxazine) materials are based on derivatives of 3,4-dihydro-2 H-1,3-benzoxazine monomers, which are readily derived from the reaction between a phenol derivative, a primary amine, and formaldehyde through a Mannich-type approach. Poly(benzoxazine)s are used widely as protective layers because of their thermal stability and mechanical properties. The chemical polymerization of benzoxazine monomers can be initiated thermally or in combination with an acid catalyst. Moreover, the electrochemically induced anodic polymerization of benzoxazine monomers can be achieved in basic acetonitrile or methanol. It is assumed that the electrochemical polymerization is induced by oxidation ; of the deprotonated oxazine ring. The formed radicals further react with the aromatic systems of the phenol moiety within the benzoxazine monomers, and propagation then leads to the formation of a dense network of a poly(benzoxazine) resin. Os complexes containing 2,2’-bipyridine (bpy) ligands are well-investigated redox mediators for the electron transfer between electrode surfaces and prosthetic groups within enzymes. The use of hydrogels modified with Os complexes allows the wiring of the enzyme to the electrode surface within a stable immobilization matrix. The redox relays within the active layer ensure a fast and efficient electron transfer between the enzyme and the electrode. Such polymers modifie