土壤pH值对冻融黑土重金属Cd赋存形态的影响.PDFVIP

业环境科学学报 园园8熏 7穴2雪:574-578 允燥怎则灶葬造 燥枣 粤早则燥鄄耘灶增蚤则燥灶皂藻灶贼 杂糟蚤藻灶糟藻 土壤pH 值对冻融黑土重金属Cd 赋存形态的影响 1袁2 1 1 1 王 洋 袁刘景双 袁王金达 袁王国平 渊1. 中国科学院东北地理与农业生态研究所袁吉林 长春 1300 12曰2. 中国科学院研究生院袁北京 100049 冤 要院冻融作用对不同土壤pH 值的重金属Cd 赋存形态的转化产生显著影响袁以24 h 为一个冻融周期袁对2.5 mg Cd 窑kg-1 的黑 土冻融8 次的实验结果表明袁pH 值6.0耀4.5 时袁冻融作用 进重金属交换态和有机结合态Cd 含量增加袁铁锰氧化物结合态和残渣 态Cd 含量降低曰pH 值6.0耀9.5 时袁冻融作用 进交换态和有机结合态Cd 含量降低袁铁锰氧化物结合态和残渣态Cd 含量增高遥 从 重金属Cd 赋存形态的转化可得袁随着土壤pH 值的升高袁冻融作用 进重金属Cd 生物有效态含量降低遥 关键词院重金属Cd 曰形态转化曰pH 值曰冻融循环曰黑土 中图分类号院X131.3 文献标识码院A 文章编号院1672-2043(2008)02-0574-05 Effects of pH on the Fraction Transformations of Cd in Phaiozem Soil at the Condition of Freeze/Thaw Cycles 1,2 1 1 1 WANG Yang 袁LIU Jing-shuang 袁WANG Jin-da 袁WANG Guo-ping (1.Northeast Institute of Geography and Agricultural Ecology, Chinese Academy of Sciences, Changchun 130012, China; 2.Graduate School, Chinese Academy of Sciences, Beijing 100049, China) Abstract: Freeze/thaw process is one of the important environment factors which can cause the soil physical-chemical and biological proper原 ties change. The impacts of pH on the Cd fractions transformation in phaiozem soil at the condition of freeze/thaw cycles (FTCs) were investi原 gated. The results indicate that FTCs can promote Cd fraction transformations at different soil pH. When the pH value is from 4.5 to 6.0, the FTCs promote the increase of exchangeable and organic matter binding fraction Cd and the decrease of iron-manganese oxides binding frac原 tion and residual fraction Cd. Adversely when the pH value is from 6.0 to 9.5, the FTCs promote the decrease of exchangeable and organic matter binding fraction Cd and the increase of iron-manganese oxides binding fraction and residual fraction Cd. The results also indicate that FTCs can cause the decrease of available Cd content with the incr