有组织排放挥发性有机物监测方法研究-以溶剂使用源为例.docx

有组织排放挥发性有机物监测方法研究:以溶剂使用源为例王红丽*, 景盛翱, 王倩, 黄成, 楼晟荣, 乔利平, 李莉国家环境保护城市大气复合污染成因与防治重点实验室，上海市环境科学研究院，上海200233摘要：本研究以上海2家修造船企业、3家汽车制造企业、2家大型涂料生产企业、1家大型油墨生产企业以及1家大型包装印刷企业为例，研究不同监测方法对溶剂使用源有组织排放废气VOCs监测的适用性；并在此基础上探讨溶剂使用源排放VOCs的组成特征。结果表明，采用Summa罐可以很好的采集和储存溶剂使用源排放的有机物，废气经Summa罐采集储存一周内，其中的非甲烷总烃（NMHC）浓度与企业现场测试结果一致性很好，二者相关系数高达0.99，比值为1.04±0.09。采用气相色谱-氢离子火焰/质谱（GC-FID/MS）联用技术分析Summa罐采集的废气，可以定量分析的VOCs组分占NMHC的60%左右（以碳计）；不同溶剂使用过程排放的NMHC中可定量组分的比例存在一定的差异，变化范围从29%到92%；在可定量VOCs组分中，芳香烃和含氧VOCs是主要组成。研究结果对于研究溶剂使用源排放VOCs的物质清单有一定支撑作用。关键词：挥发性有机物, 溶剂使用, 非甲烷总烃, 监测Volatile Organic Compounds (VOCs) Measurements in Industrial Emissions: Case Study of Solvent Use Emissions in Shanghai, ChinaWANG-Hong-li, JING Sheng-ao, WANG Qian, HUANG Cheng, LOU Sheng-rong, QIAO Li-ping, LI LiState Environmental Protection Key Laboratory of Formation and Prevention of the Urban Air Complex, Shanghai Academy of Environmental Sciences, Shanghai 200233, ChinaAbstract:Volatile Organic Compounds (VOCs) measurement is complex due to the various species and chemical reactivity, which is more challenging under the conditions of industrial exhausts. In this study different measurement methods were employed to monitor VOCs emissions from industrial solvent useand stainless-steel Summa canisters sampling wasproved to besuitable for the collection and storage of solvent VOCs emissions for scientificpurpose. Non-methane hydrocarbons (NMHC) concentrations of canister samples were measured by GC-FID-MS analysis right after the collection and one week after collection. The results showed good consistency with an linear correlationfactor of 1.04±0.09 (R2=0.99 ).Measured NMHC can be quantified by VOCs species for about 60% in average by means of GC-FID-MS analyses. The value varied from 0.29 to 0.92insamples from different industries. Aromatics and oxygenated VOCs were dominated speciesin quantified VOCs species. The result can be applied to further research inemission inventory of industry solvent use.Keywords: volatile organic compound