基于阻抗测量的水泥浆体早期水化过程特征研究.pdfVIP

第 19 卷第 6 期 建筑材料学报 Vo l. 19 ,No. 6 2016 年 12 月 JOURNAL OF BUILDING MATERIALS Dec. ,2016 文章编号:1007-9629(2016)06-1051-06 基于阻抗测量的水泥浆体早期水化过程特征研究 王倚1 ， 2 ，吴瑾1 (1.南京航空航天大学土木工程系，江苏南京 210016; 2. 连云港职业技术学院建筑工程系，江苏连云港 222006) 摘要:采用非接触式阻抗测量法(NCIM) ，研究了水泥浆体的早期水化过程及其在不同阶段的水化 行为，并通过 Kramers-Kronig 变换验证了阻抗数据的可靠性.结果表明:在溶解阶段及动态乎衡阶 段水泥浆体的阻抗近似为纯电阻;在加速阶段水泥浆体中的阻抗虚部值随着频率的增加而增加; 水泥浆体早期抗压强度与其阻抗模数有很好的线性关系. 关键词:水化;水泥浆体;阻抗测量; Kramers-Kronig 变换 中图分类号:TU528.01 文献标志码:A doi:10. 3969/j. issn.1007-9629. 2016.06.017 Characterization of Early-Age Hydration Process of Cement Pastes ßased on Impedance Measurement l 2 l WANG Qian • , WU ]in (1. Department of Civil Engineering , Nanjing University of Aeronautics and Astronautics , Nanjing 210016 , China; 2. Department of Architectural Engineering , Lianyungang Technical College , Lianyungang 222006 , China) Abstract: The hydration process of cement pastes was investigated by using non-contact impedance measure- ment(NCIM). The reliability of impedance data from NCIM was checked by classical Kramers-Kronig trans- formation. Hydration behaviors of pure cement paste in different stages(dissolution , competition and accelera- tion stages) were interpreted by NCIM. It is found that the impedance response of cement pastes is approxi- mately resistive in the dissolution and competition stage. Experimental and calculated imaginary parts of impedance of cement pastes in the acceleration stage increases as frequency increases. Furthermore , the early- age compressive strength of cement pastes