Fe_OH_3改性PVDF膜的制备与其抗污染性能.pdfVIP

2009 4 o.l 15 No. 4 Fe(OH) PVDF 3 邱 恒 (, 201620) : 通过过滤涂膜的方法把氢氧化铁(Fe(OH) )胶体涂在聚偏氟乙烯( PVDF)膜表面进行膜 3 的表面改性, 研究 制膜压力Fe(OH) 胶体浓度对改性膜性能的影响在制膜压力 0. 15MPa, 3 2 Fe(OH) 胶体质量分数 0. 05%的条件下, 制得的改性膜纯水通量为 350 mL /( cm h) 左右, 截留 3 率超过 99% , 高于未改性膜在膜生物反应器 (MBR) 中, 改性膜的出水水质优于未改性膜污染 膜清洗后, 改性膜纯水通量恢复率高出未改性膜 12%; 通过扫描电镜 ( S M ) 分析亦表明, 改性 PVDF膜抗污染性能提高 : 氢氧化铁胶体 聚偏氟乙烯膜 表面改性 抗污染性 : TQ028. 8+ X703 : A : 1674- 0254( 2009) 04- 0001- 05 Preparation forPolyvinylidene FluorideM embraneModified by FerricHydroxide and itsAnti- pollution Performance Q IU Heng ( College of nvironmental Science ngineering, DonghuaUniversity, Shanghai 201620, China) Abstract: In the paper, polyvinylidene fluoride membrane surface is coated w ith ferric hydroxide colloid tomodify themembrane surface performance by filteringmethod. The effects ofpressurewhile producingmembrane and concentration of ferric hydroxide colloid upon modified membranewere in vestigated. When the pressure ofmembrane preparation was 0. 15MPa and themass fractions of fer 2 ric hydrox idewas 0. 05%, themembrane pure water flux was about 350 mL /( cm h) w ith rejection rate above 99%, higher than unmodifiedmembrane. The quality of effluent treated bymodifiedmembranewasbetter than unmodifiedmembrane inmembrane bio- reactor. A fter cleared, the purewater flux recovery ratio of