单分散碳球的制备及其表征.pdfVIP

• 14 • 2014 年 1 月(下)第 28 卷第 1 期 材料导报B: 研究篇 单分散碳球的制备及其表征祷 曾祥云，杨万里，杨娇，高美珍 (兰州大学物理科学与技术学院，磁学与磁性材料教育部重点实验室，兰州 730000) 摘要 用溶剂热法合成了直径从 500 nm 到 10 阳、尺寸均匀的单分散C 球。研究了葡萄糖溶液浓度和反应 时间对C球直径的影响。分Jl) 用 SEM、 TEM 和 EDX 对C .l求的形貌和成分进行了表征，用差热法分析了 C 球的热稳 定性。随着葡萄糖浓度的增加和反应时间的延长，C 球的直径增加，但是不是无限制的。通过对C 球进行表征，提出 了 C球生成的机理，证明 C 球是由 C 纳米颗粒组成的多孔的表面光滑的实心球。 关键词 溶剂热法 C球模板多孔 中固分类号:TQ127.1+1 文献标识码:A The Preparation and Characterization of Monodispersed Carbon Spherules ZENG Xiangyun , YANG Wanli , YANG Jiao , GAO Meizhen (Key Laboratory for Magnetism and Magnetic Materials of Ministry of Education , College of Physical Science and Technology , Lanzhou University , Lanzhou 730000) Abstract Uniform and monodispersed carbon spherules were prepared through solvothermal method. The dia- meters of the spherules range from 500 nm to 10μm depending on the reaction time and concentration of glucose in the solution. The morphology and composition of the carbon spherules were characterized by SEM , TEM and EDX , the thermogravimetric performance was analysed by TGA The results show that the dimension of the carbon spherules increases with increasing reaction time and concentration of the glucose. The carbon spherules are porous , smooth and solid , and are composed of nanoparticles. The formation mechanism of the carbon spherules was also proposed. Key words solvothermal method , carbon spherules , template , porosity 0 引言 1 实验 近年来，纳米及微米尺度的空心和多壳层金属氧化物球 1. 1 C 球的制备 成为了新的研究热点。多壳层结构金属氧化物由于具有大 制备C 球所用的药