第九章卤代烃.pptVIP

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  • 2017-06-10 发布于四川
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Organic Chemistry 2) 复杂卤代烃的命名用系统命名法: 以相应的烃为母体,卤原子为取代基; 饱和卤代烃以烷烃名称为基础 , 选含卤原子的最长碳链为主链,并从卤原子开始编号; 2.2 光谱性质 1、IR 2、NMR Chemical Properties Hydrolysis Chemical Properties a. Hydrolysis – cont. Side product : alkene (From dehydrohalogenation) Chemical Properties Elimination: Dehydrohalogenation That is, dehydrohalogenation reaction when alkyl halide is heated with a strong base using a relative non-polar solvent. Saytzeffrule(查依采夫规则): Saytzeffrule (查依采夫规则) Elimination: Dehydrohalogenation (cont.) ? Note that both base and nucleophile are electron rich species, hence both elim

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