art染料化学.pdf

Mat Res Innovat (2002) 5:277–283 DOI 10.1007/s10019-002-0162-x O R I G I N A L A RT I C L E Tatjana Kreze · Slava Jeler · Simona Strnad Correlation between structure characteristics and adsorption properties of regenerated cellulose fibers Received: 23 October 2001 / Accepted: 13 December 2001 / Published online: 16 April 2002 © Springer-Verlag 2002 Abstract We correlate fine structure with the adsorption and morphology. Much less is known about the correla- behavior of new (lyocell) and conventional (viscose, tion between the structure of fiber and their behavior modal) regenerated cellulose fibers. We have studied the during the finishing processes. The properties of fibers in molecular structure, the fine structure and, most impor- the swollen state are of major interest. Accessibility in tant of all, the amorphous regions and voids in the the water-swollen state is of even greater importance system. Differences in adsorption properties of all three- than accessibility in the dry state for many industrial pro- fiber types were determined by using several methods cesses on cellulose fibers. Under these circumstances the for quantification of water, dye and iodine adsorption. less ordered regions determine the fiber properties and, The structural analysis shows that higher molecular therefore, the accessible amorphous regions and void weight, a higher degree of crystallinity and a higher fraction are supposed to be responsible for the reactivity molecular orientation are found in lyocell fibers [1]. Our and adsorption processes. The accessibility of cellulose results obtained by several independent methods demon- t