第十章计算题参考谜底(国外英文资料).docVIP

第十章计算题参考答案(国外英文资料) The tenth chapter, calculation questions, reference answers 9. in the production of polyester resin, known polycondensation temperature is 280 DEG C (esterification equilibrium constant K=4.9 of this temperature), to system number average molecular weight of polyester resin 20000, find the maximum vapor pressure in the reaction kettle to ethylene glycol (280 DEG, saturated vapor pressure of ethylene glycol P0 = 5.776mmHg). Answer: polyester resin, that is polyethylene terephthalate, the structural unit of the molecular weight of: 192/2=96 So???????? 20000/96 = 208 By the formula:????????????? NW? 1.13 x 10-4 mol/L That is, the maximum allowable vapor pressure of ethylene glycol in the kettle is Ps=0.65mmHg = 86.66Pa The reaction equilibrium constant K 10. at 280 DEG C = 4.9, C 260 poly amidation reaction equilibrium constant K = 305, try the water content (mole fraction representation) and number average polymerization degree diagram, and discuss the analysis of its results. Answer: according to... Simultaneous solver: ???? (to have negative) So there is a reaction to polyester Reaction to polyamides As the map of water content assignment: ? It can be seen from the diagram that the water content in the polycondensation reaction has a great influence on the logarithmic mean molecular weight, especially when the equilibrium constant is small, the water content has a very serious influence on the degree of polymerization. In order to obtain a higher degree of polymerization, for example, about 200, the residual small molecular by-products must be extremely low. However, for the condensation polymerization with larger equilibrium constant, the content of small molecular by-products can be higher, so that the removal of small molecular by-products can be relaxed. 11. manufacture of nylon -66, in order to maintain the adipic acid and hexanediamine etc. are usually the first to make the two molar ratio, salt, and then to 254 C (K=300) polycondensation.