石墨烯包裹Fe3O4作为锂离子电池的负极材料.ppt

Graphene-Wrapped Fe3O4 Anode Material for Lithium Ion Batteries Applications for Lithium ion battery High energy density: small volume huge energy High voltage: reduce the number of series battery Good cycle performance: long service life(1000times) No memory effect: charge and discharge at any time Environmental friendly Advantages of Li-ion battery Simple principles of the Li-ion battery Carbon material LiTiO Tin oxide Metal oxide (Co Ni Fe Cu) Compound material Anode material for Li-ion battery Fe3O4 Advantages: High specific-capacity(924mAh/g) Higher potential High electronic conductivity Disadvantages: Severe aggregation Huge volume change What we are doing ? What we are doing ? Step1: synthesis of GNSs Synthesis of the GNS/Fe3O4 material Natural flake graphite powder Oxidated natural flake graphite Oxidated natural flake graphite GNSs oxidation Expansion exfoliation hydrogen alkali 1050℃ Ar atmosphere FeCl3 0.05mol/L 150mL 50mg GNS sonication 1h hydrolysis 353K 12h GNS/ FeOOH dry vacuum 363K 24h Heat-treat 873K Ar atmosphere GNS/Fe3O4 Step2: synthesis of GNS/Fe3O4 composite Synthesis of the GNS/Fe3O4 material Results and Discussion a) X-ray diffraction of the GNS/Fe3O4 Results and Discussion b) Raman spectra of the GNS/Fe3O4 Results and Discussion c) SEM of the GNS/Fe3O4 Commercial Fe3O4 GNS/Fe3O4 Results and Discussion Judged by the a,b and c test above, we did synthesised the GNS/Fe3O4 layer-by-layer structure material expected before Results and Discussion Electrochemical performance of the GNS/Fe3O4 Results and Discussion Why did the GNS/Fe3O4 works well? Prevent the aggregation of Fe3O4 particles Enwrap Fe3O4 particles, reduce detachment(provide buffering space against the volume change) Porosity facilitates ion transportation Synthesised the layer-by-layer structure GNS/Fe3O4 anode material. The GNS/Fe3O4 material has a better electrochemical performance than the commercial Fe3O4 :a capacity of 950mAh/g and a better cycle stability. Analy