改进的QuEChERS方法配合GPC_GC_MS在线联用系统测定果蔬中31种农药.pdfVIP

2011 2 21 2 Chinese Journal ofH ea lth Laboratory Technology, Feb 2011; Vol 21 No 2 277 改进的QuEChERS方法配合 GPC- GC- M S在线联用系统测定 果蔬中 31种农药残留 李琰, 蔡跃, 杨胜琴, 绪红霞, 仓书华, 黄向荣, 计文芳 ( , 201101) [ ] : 31: QuEChERS GPC- GC - MS , 31: 31 ; ( S/N!3) 0. 01g/ g~ 0. 83g/ g; 72% ~ 110% ; 1. 6% ~ 10% : , [ ] QuEChERS; 凝胶渗透色谱; 气相色谱- 质谱法; 农药 留; 果蔬 [ ] O657 [] A [ ] 1004- 8685( 2011) 02- 0277- 04 Determ ination of31 pesticide residues in fruits and vegetables using a on- lineGPC- GC - MS system combined withmodified QuEChERS LI Yan, CA I Yue, YAN G Sheng - q in, X U H ong - x ia, CAN G Shu - hua, H UAN G X iang - rong, JI W en -f ang ( M inhang C enter for Disease Con trol and Prevention, Shanghai 201101, China) [ bstract] Objective: To estab lish a m ethod for determ ination of 31 pesticide residues in fru its and vegetab les. M ethods: M od ified QuEChERS pretreatm ent m ethod and a on- lineGPC- GC- M S system w ere used for the rap id determ ination of 31 pes ticide residues includ ing organophosphorus, organochlorine, carbam ate and pyrethroid etc. Results: The 31 pesticideswere well separated and the detection lmi its of them ethodw ere 0. 01g / g~ 0. 83 g / g, the recoveriesw ere 72% ~ 110% and the rela tive standard deviationswere 1. 6% ~ 10% . Conclusion: The good sens itivity , precision , accuracy, smi p le operation and short analytical period of this m ethod cou ld satisfy the requirem ent of smi u ltaneous determ ination of various pesticide residues. [Keywords] QuEChERS; Gel permeation chrom atography; Gas chrom atography - m ass spectrom etry; Pesticide residues; Fru its and vegetab les , (); : Shodex CLNpa EV- [ 1]