物理化学-习题课课件-第5章.pdfVIP

1、已知298.15K时下列物质的 H 和S  ： f m m 物质 CO(g) CH OH(g) CH OH(l) H (g) 3 3 2   H /(kJ/mol) -110.505 -200.66 0 f m  S /(J /mol/k) 197.674 126.8 130.684 m 求298.15K时下列反应的K CO(g)2H (g) CH OH(g) 2 3 已知298.15K 甲醇的饱和蒸汽压为16.59 kPa，蒸气 可视为理想气体，且  H 38.0kJ /mol vap m g CH OH(l)  Sl CH OH(g) 3 3 298.15K 298.15K 16.59kPa 16.59kPa ΔS1 ΔS2 CH OH(l) ΔS CH OH(g) 3 3 298.15K 298.15K 100kPa 100kPa   S (CH OH,g) S (CH OH,l)S m 3 m 3 g 1 S S  SS 1 l 2 S  0 1 38.01000 g  S 127.45J /mol l 298.15 p1 S nRln 14.94J /mol 2 p2 S 112.51J /mol  S (CH OH,g) 126.8112.51 239.31J /mol m 3  S 239.31197.6742130.684 219.73J /mol r m  H 200.66110.525 90.135J /mol r m     G  H T S 90.135298.15(219.73)/1000 r m r