食品包装材料油墨成分的迁移及溶出.docVIP

食品包装材料中油墨成分的迁移及溶出 摘　　要 采用食品模拟物进行迁移实验，结合固相微萃取-气相色谱质谱联用技术（SPME/GC-MS），建立了食品包装材料印刷油墨中两种光引发剂溶出量的测定方法。研究了迁移温度和时间对光引发剂迁移的影响，以纯水和10%乙醇-水为食品模拟物，在4℃和45℃下迁移120min。模拟液用固相微萃取（SPME）技术进行萃取，对萃取头、萃取温度和时间进行了优化。利用GC-MS对目标物进行定量分析。结果表明，二苯甲酮和4-甲基二苯甲酮在0.03μg/L～1.0μg/L的范围内线性关系均良好（r2≥0.99），检测限分别为0.0012μg/L、0.0040μg/L。两种目标物在三个添加水平下，平均回收率为75.1%～95.6%，相对标准偏差均小于11.5%。本方法 关键词：食品包装材料；食品模拟物；气相色谱质谱法；光引发剂；迁移实验 Migration and dissolution of components in printing ink of food packing materials ABSTRACT Food stimulant and solid phase microextractiongas chromatography-mass spectrometry (SPME/GC-MS) were used in the abstraction experiment. A method for the determination of two kind of photoinitiators migrated from the printing ink on the surface of food packaging material has been developed. Photoinitiators in the food packaging samples were abstracted with food stimulant at the condition of 4℃、45℃、120min. The influence of temperature and time were for photoinitiators’ abstraction was studyed. Abstract was extracted by a solid phase microextraction （SPME）technology. Extraction-fiber, temperature and time were optimized. The target was analysised by GC-MS. The results showed that, the limit of detection for benzophenone and 4-methyl benzophenone was 0.0012μg/L and 0.0040μg/L with a good linear correlation (r2≥0.99) in the range of 0.03μg/L～1.0μg/L.The average recoveries of the two compounds at three spiked level of were 75.1%～95.6%, with the relative standard deviation Keywords:Food packaging material；Food stimulant ；Gas chromatography-mass spectrometry；Photoinitiator；Abstraction experiment 目　　录 TOC \o 1-3 \h \z \u HYPERLINK \l _Toc325879917 1　前言 PAGEREF _Toc325879917 \h 1 HYPERLINK \l _Toc325879918 1.1　食品安全问题 PAGEREF _Toc325879918 \h 1 HYPERLINK \l _Toc325879919 1.2　油墨中的光引发剂 PAGEREF _Toc325879919 \h 1 HYPERLINK \l _Toc325879920 1.3　食品模拟物 PAGEREF _Toc325879920 \h 1 HYPERLINK \l _Toc325879921 1.4　国内外对光引发剂迁移的研究 PAGEREF _Toc325879921 \h 2 HYPERLINK \l _Toc325879922 1.5　本实验研究内容及意义 PAGEREF _Toc3