【2017年整理】淀粉的FTIR测定实例.pptVIP

淀粉的FT-IR检测实例Fourier Transform Infared Spectroscopy;内容;R KIZIL, J IRUDAYARAJ, AND K SEETHARAMAN, Characterization of Irradiated Starches by Using FT-Raman and FTIR Spectroscopy, J. Agric. Food Chem. 2002, 50, 3912-3918;Table 1. Band Assignments for Infrared Spectra of Starch;Yu Jiugao, Wang Ning, Ma Xiaofei, The Effects of Citric Acid on the Properties of Thermoplastic Starch Plasticized by Glycerol, Starch/St?rke 57 (2005) 494–504 ;表1 　红外吸收波数对应的与氢键形成有关的基团以及Δf 的变化;Absorbance spectra were recorded on a Perkin Elmer spectrophotometer equipped with a DTGS (deuterated triglycine-sulfate) detector. Samples were prepared with 6% (w/w) CLA powders (particle size below 50 mm) dispersed in KBr pellets (100 g). All powders were dried at 105?C for 24 h before tableting with KBr and several CL-amyloses, of different clds, were used. Typically, 256 scans were recorded with a 4 cm-1 resolution. For the calculation, the absorbance of the bending mode of the water detected at 1646 cm-1 was normalized by dividing the peak area (1646 cm-1) by the peak area of the CH2 modes at 2928 cm-1. The latter was corrected for the water contribution by using spectral deconvolution.;Evaluation only. Created with Aspose.Slides for .NET 3.5 Client Profile 5.2.0.0. Copyright 2004-2011 Aspose Pty Ltd.;从纯淀粉的红外图谱（图1）中可以看出，在3000~4000cm-1有淀粉-OH的伸缩振动峰，在859cm-1、760cm-1、572cm-1处有淀粉的-CH2的摇摆吸收峰。;2. C—O Bending Vibrations;Fig. 3. FTIR spectrum of amylose in the 1300–850 cm-1 region. The spectral simulation and residual noise are also shown.;Fig. 4. Variation IR positions of four peaks, determined after spectral simulation, with increasing pH. See text for details. The error bars represent the standard deviation from at least five samples. ;?sa Rindlav, Stephan H.D. Hullernan and Paul Gatenholm, Formation of starch films with varying crystallinity, Carbohydrate Polymers 34 (1997) 25-30 ;Fig. 3. Deconvoluted ATR-FTIR spectra of potato starch films with increasing crystallinity from top to bottom. Spectra normal