金属卟啉复合的介孔SiO2纳米粒子催化剂的制备及性质.pdf

催化剂的转化数为45857；它在对环己烷的催化氧化过程中，环己烷的转化率达到 450／,，催化剂的转化数为95658。 关键词：介孔材料MCM-41金属卟啉合成负载催化氧化 Ⅱ Abstract to the ofthewell-knownwith for Update,most hi曲activityepoxidation catalysts andoxidationofalkaneare ofalkene composed oxidationstationin the砖甜ti∞ W(VI)andTi(IV)，etc．，withlligh complex鹤andusually conditions harsh oxidation a糟very employed during出c∞蝴c derivaliveshavebeen usedasthemodel of P-450 cytochrome widely compounds inthe of oxidation usedas monooxygenase V商ol塔catalyticreactions，usually study biomimic in themeritsofmoderate solutions,which catalystshomogeneous possess reaction andSO011．n蝣main isthe conditions．hi【ghactivity,selectivity shortcoming forthe of reaction for USC． the recovery systemrecycle difficulty catalysts丘哪the as ontoinsolublesolidsuch Therefore,loadingofmetailoporphyrincatalyst mesoporous as inthis field． materials atU-∞ts attentionresearch catalysts heterogeneous great ThisdissertationfocusesOnthe of andtheir