静电纺再生大腹圆蛛牵引丝后处理的性能.PDFVIP

安徽农业大学学报, 2015, 42(6): 1011-1014 Journal of Anhui Agricultural University [DOI] 10.13610/ki.1672-352x008 网络出版时间：2015-11-2 15:34:36 [URL] /kcms/detail/34.1162.S1534.016.html 静电纺再生大腹圆蛛牵引丝后处理的性能 1 2 刁均艳 ，潘志娟 (1. 安庆职业技术学院，安庆 246000 ；2. 苏州大学纺织与服装工程学院，苏州 215021) 摘 要：探讨以六氟异丙醇（HFIP ）为溶剂时，静电纺大腹园蛛牵引丝纤维（AVSHF ）纤维毡经去离子水处 理后的尺寸及性能变化。结果表明，静电纺再生大腹园蛛牵引丝纤维遇水则发生严重的收缩（收缩率 45 % ），对其 用 99%的乙醇处理后，在水中的形态稳定性得到了改善（收缩率 10% ），处理后纤维的分子构象有明显β-折叠结 构转化的趋势，纤维的结晶度以及断裂强度分别较原样提高了 5.5%和 23% 。 关键词：蜘蛛丝；静电纺丝；形态稳定性；分子构象；力学性能 中图分类号：TS102.33 文献标识码：A 文章编号：1672−352X (2015)06−1011−04 Performance of post-treatment of electrospun regenerated Araneus ventricosus spider silk 1 2 DIAO Junyan , PAN Zhijuan (1. Anqing Vocational and Technical College, Anqing 246000; 2. College of Textile and Clothing Engineering, Soochow University, Suzhou 215021) Abstract: Change of size and performance of water-treated nonwoven fabric of regenerated Araneus ven- tricosus spider silk （AVSHF ）in the hexaflorisopropanol (HFIP) solutions were studied. The results show that electrospun AVS dragline silk shrunk seriously in water (contraction 45%); however, improvement was observed after being treated with 99% ethanol (contraction 10%). The molecular conformation of the treated fiber showed a tendency of the β-sheet structure transformation. The crystal degree and breaking strength of the fiber were im- proved by 5.5% and 23%, respectively compared with the original sample. Key words: spider silk; electrospinning; morphologic stability; molecular conformation; mechanical per- formance 大腹圆蛛牵引丝难以直接利用，需通过静电纺 将其再生加工为可直接使用的纤维毡形式 [1-3]