基于CO释放速率的煤自燃阻化剂试验研究.pdfVIP

2015年 第 8 期 中州煤炭 总 第 236期 基 于 C O 释放速率的煤自燃阻化剂试验研究 谢锋承 (河南能源化工集团义煤公司千秋煤矿，河南义马 472300) 摘 要 ：为了研究阻化剂对煤的阻化特征，在搭建小型试验平台的基础上，采 用 PG -250A 烟气分析仪，连续测 定了 3 种煤加入阻化剂前后，150 T ：低温氧化过程中的C O 释放量。结果显示：MgCl2 的阻化作用前期优于 后期，抗氧剂 A 的阻化作用后期优于前期，2 号凝肢在整个氧化过程中有优良的阻化效果。研究表明：3种 阻化剂的阻化规律不同，对同一煤样的阻化效果也不尽相同；并且由于煤质的差异，同种阻化剂对各煤样的 阻化效果也有差别；3 种阻化剂的阻化作用由强到弱为：2号凝肢、MgCl2、抗氧剂 A 。 关 键 词 ：煤 ；氧化与阻化；C O 释放速率；阻化率；阻化效能 中图分类号：TD 752.2 文献标志码 ： A 文章编号 ： 1003 -0 5 0 6 (2 0 1 5 ) 08 -0 0 1 1 - 0 4 Experiment Study on Inhibitor of Coal Spontaneous Combustion Based on CO Release Rate Xie Fengcheng ( Qianqiu Coal M ine , Yima Coal Company, Henan Energy Chemical Industry Group Co. , Ltd. , Yima 472300, China) Abstract ：To study inhibitory character of inhibitor to coal for preventing coal spontaneous combustion, based on building a small-sized experiment platform and using advanced gas analyser PG -250A , CO yields of three kinds of coals with different properties was deter­ mined continuously in the process of low tem perature(150 X, ) before and after adding different inhibitors. Results display th a t ：MgCl2 has better inhibitory effect in earlier stage than in later stage ； conversely Antioxidant A has better inhibitory effect in later stage than in earlier stage； Gel 2 has eximious inhibitory effect in the whole oxidation progress. Study indicates th a t： the three inhibitors have different inhibitory law s, their inhibitory effects to the same coal sample are not so identical ； in addition, because of the difference of coal proper­ ty, the same inhibitor^ inhibitory ef