ABS装置BL单元工艺设计.doc

PBL工艺区域生产聚丁二烯胶乳（PBL）,它是聚丁二烯橡胶在水中的一种乳化液，作为HRG区域中生产树脂的原料。 生产PBL分为5个工艺步骤： A 准备进料 B 反应 C 闪蒸未反应的丁二烯 D 均质 E PBL储存 准备进料阶段包括从丁二烯单体中去除抑制剂，制备批次加入的溶液、乳化剂和反应催化剂，和在反应的结束后回收未反应的丁二烯循环使用。 反应区域由平行安装的5台相同的反应釜组成，采用程序操作。批次加入一定数量的无离子水、乳化剂、反应催化剂溶液和部分丁二烯单体。经过升温后，反应开始，在后续反应中计量加入丁二烯、引发剂和链转移剂。当丁二烯进料完成，反应器温度上升开始精致阶段，使剩下的丁二烯反应近乎完全，此后，冷却反应器夹套，粗PBL溶液进入闪蒸阶段。反应周期总计约10-13小时，包括进料、反应、输送反应后组分和为下次进料做准备的时间。 为了能从粗PBL中去除未反应的丁二烯单体，需要在受控的真空条件下操作闪蒸罐。丁二烯经过回收，循环进入进料准备单元，同新鲜丁二烯单体一起进料。 泵将粗PBL从闪蒸罐输送至均值单元。在这里，乳胶橡胶粒径增加，粒径分布达到用于HRG反应的要求。该操作包括粗乳胶中间品储罐、均质机进料罐、泵和均质机。4台均质机平行连续进料。 关键字：乳化液,连续进料,闪蒸 Abstract The PBL process area makes Polybutadiene Latex (PBL),an emulsion of polybutadiene rubber in water that is used as a row material to make resin in the HRG process area. Feed preparation Reaction Flash removal of unreacted butadiene Homogenization PBL storage Feed preparation includes the operations of removing inhibitor from butadiene monomer preparation of batch solutions,an emulsifierand reaction catalysts,and recover of unreacted butadiene from the end of the processfor recycle. Reaction area consists of five identical reactor installed in parallel.which operate in rsequence.A reactor is charged with batch quantities of demineralized water,emulsifier,reaction catalysts solution,and a partial charge of butadiene monomer.After heat up and initiation of reaction,butadiene,initiator,andchain transfer agent are metered to the reactor as the reaction proceeds.After the butadiene feed quantity is complete,reactor temperature is increased for the polishing step,which polymerizes the remaining butadiene to near-compltion.The reactor contents are then cooled before transferring the crude PBL solution to the Flash step.The total reactor cycle is 12-13 hours,including the steps of filling,reacting,transfer of reacted contents,and preparation for the next charge. The flash Tank operates under a controlled vacuum in order to remove unreacted butadeiene monomer from the crude PBL.The butadiene is recovered and recycled to the feed