微胶囊包覆磷钼酸铵的制备、表征及在UPR中阻燃抑烟性能研究.doc

微胶囊包覆磷钼酸铵的制备、表征及在UPR中阻燃抑烟性能研究汪关才，胡小平，卢忠远**，宋丽贤，张明江，张建华，陈丰 (西南科技大学材料科学与工程学院，四川 绵阳 621002) 摘要：用原位聚合法制备了蜜胺甲醛树脂微胶囊并对合成磷钼酸铵(AMP)进行包覆。SEM结果表明n(蜜胺):n(甲醛)=1.0:2.5，pH=2.5，温度为70℃的条件下反应3h后，再将pH升至6.0，所磷钼酸铵(MCAMP)中位径7.709μm，胶囊壁呈葡萄串形结构且；(MCAMP)=5%将MCAMP添加到不饱和聚酯树脂(UPR)中，UPR氧指数(LOI)从纯树脂的%上升至25.2%，UL94达V-级烟密度等级(SDR)从75.25降至65.11最大烟密度(MSD)从95.73下降至89.24，满足国家对B1级电类热固性塑料的使用要求。关键词：磷钼酸铵；不饱和聚酯树脂；微胶囊；阻燃；抑烟 中图分类号：O612.4；TQ325.3 文献标识码： 文章编号： Preparation and characterization of ammonium molybdophosphate coated by microcapsule and flame retardancy, smoke suppression of its composites with UPR WANG Guan-cai, HU Xiao-ping, LU Zhong-yuan, SONG Li-xian, ZHANG Ming-jiang, ZHANG Jian-hua, CHEN Feng (School of Material Science and Engineering, Southwest University of Science and Technology, Mianyang 621002, China) Abstract: Ammonium molybdophosphate(AMP) was synthesized and coated by melamine-formaldehyde resin microcapsule with in situ polymerization. The results of diameter distribution and SEM indicated that ammonium molybdophosphate encapsulated by melamine-formaldehyde resin(MCAMP) had good dispersiveness, d(0.5)=7.709μm and grape-bunch structure on the condition that n(melamin):n(formaldehyde)=1.0:2.5, pH=2.5, 70℃, reaction time of 3h and later the value of pH ascended to 6.0. ω(MCAMP)=5% applied to unsaturated polyester resin(UPR), limited oxygen index(LOI) of composite came to 24.6% from 20.0% of pure UPR, UL94 flame retardancy to UL94V-2, smoke density rate(SDR) to 65.11 from 75.25 and maximum smoke density(MSD) to 90.81 from 95.73. These properties were satisfied to the application for thermoset wiring of B1 rate. Keywords: ammonium molybdophosphate; unsaturated polyester resin; microcapsule; flame retardance; smoke suppression 不饱和聚酯树脂(UPR)因价格低廉、成型方便、性能优良等特点已广泛应用于建筑、船舶、汽车以及电器件等领域[1]，但其LOI仅为%，属于易燃产品，同时由于其碳、氢元素含量高且主链垂挂大量的芳香基团，燃烧时会发出大量的烟和有毒气体[2]。据报告，火灾中80%的死亡者是由聚合物材料燃烧放出的烟和有毒气体所造成的[3]，因此研究UPR的阻燃及发烟问题，开发的UPR阻燃复合材料，已成为推广UPR应用的一项重要内容。 目前用于UPR阻燃的主要有[4]、[5]、