PH值的测定—玻璃电极法(国外英文资料).doc

PH值的测定—玻璃电极法(国外英文资料) Water quality - the measurement of PH value - glass electrode method Water quality - the measurement of PH value - glass electrode method Water Quality - Oetermination of pH Value - Glass Method 1 scope This law applies to the determination of pH of water, surface water and industrial wastewater. The color, turbidity, colloid matter, oxidant, reductant and high salt content of water are not interfered with measurement; But in a strong acidic solution of pH 1, there is a acid error that can be determined by acidity; In the alkaline solution of pH 10, there is a large amount of sodium ions present, causing the error and low readings, commonly referred to as sodium difference. Eliminate the method of sodium bad, in addition to using a special low sodium poor electrode, but also like selection and the pH of the test solution similar standard buffer solution for instrument calibration. The temperature affects the potential of the electrode and the ionization of the water. Must pay attention to adjusting the instrument of compensation device and the solution temperature, and make the sample under test and calibration instruments with standard buffer solution temperature error is within + / - 1 ℃. Definition 2 The pH is defined by the operation. For solution x, we measured the electromotive force of 1 kc1 concentrated solution of the galvanic cell. Change the solution X of the pH (X) to the standard pH solution S, and also measure the electromotive force of the cell PH (X) = pH (S) + (Es - Ex) F/(RTIn10). So, the defined pH is the dimensionless quantity. PH has no theoretical meaning, which is defined as a practical definition. However, when the concentration of material is less than 0.1 mo1.dm, the thin aqueous solution of dm-3 is neither strongly acidic nor strongly alkaline (Z pH 12), it is defined by definition PH = -log 10 [C (H +) y/(mo1. Dm3)] C (H +) represents the concentration of the substance of hydrogen ion H +, which is typical of 1 i