温敏性聚合物P_AM_Macromer_及其与表面活性剂的复合性能(国外英文资料).doc

温敏性聚合物P_AM_Macromer_及其与表面活性剂的复合性能(国外英文资料) According to AM: Macromer is a ratio of 9 to 1 and the proportion of AM and Macromer, which is used for a second distilled water A water solution with a mass fraction of 30%. The monomer The solution into equipped with electromagnetic stirrer and at 40 ℃ constant temperature water In the three neck bottles of the bath, the N230 min is added to the 0.1 percent K2S2O8 / NaHSO3 (per unit mass, K2S2O8) NaHSO3 = 2:1), the aggregation reaction 8h. The resulting polymerization With acetone precipitation after soluble in water and sediment in 40 ℃ dry vacuum The dry hours are in reserve. 1.3 solution performance testing Using the German kruss-kiost digital surface tensiometer On the surface tension of solution, temperature 20 ℃ ~ 80 ℃; mining Use the Gemini 200 of Malvern Instruments in the UK Type dynamic rheometer is used to determine the surface viscosity of polymer solution with temperature Condition of change (measurement condition: the shear rate is one/s, heating up Rate of 2 ℃ / min, the test temperature is 20 ℃ ~ 85 ℃); By Brookfield Ⅲ composite solution viscosity meter measuring table Concept of viscosity, temperature, precise control of plus or minus 0.1 ℃, the shear rate is zero 10 / s. Fig. 1 Influence of temperature on view Viscosity of P (AM - Macromer) Results and discussion The 2.1 temperature is viscous to the water solution of am-macromer The influence of the degree of Fig. 1 is P (AM -) that has a mass score of 0 Macromer, copolymer solution and the addition of 0.2% NaCl The surface viscosity of saltwater solution varies with temperature. With the temperature The rise of am-macromers copolymer solution looks sticky The trend is rising, indicating that P (AM - Macromer) is available A temperature sensitive aqueous polymer. Add in the polymer solution After NaCl, the temperature increase is at a lower temperature Show. This shows that P (AM - Macromer) is in an aqueous solution Temperature sensitivity is associate