熔融碱法从红土镍矿中提取硅的方法.pdfVIP

第 19 卷第 3 期 中国有色金属学报 2009 年 3 月 Vol.19 No.3 The Chinese Journal of Nonferrous Metals Mar. 2009 文章编号：1004-0609(2009)03-0570-06 采用熔融碱法从红土镍矿中提取硅 牟文宁，翟玉春，刘 岩 (东北大学 材料与冶金学院，沈阳 110004) 摘 要：通过正交试验，研究红土镍矿熔融碱法提硅过程中反应温度、反应时间、碱矿质量比及搅拌速度对 SiO2 提取率的影响。结果表明：试验过程中各因素对 SiO 提取率的影响由大到小的顺序为反应温度＞反应时间＞碱矿 2 质量比＞搅拌速度；最佳的试验条件为反应温度 550 ℃，反应时间 20 min，碱矿质量比 4׃1，搅拌速度 400 r/min； 按照最佳条件进行实验，SiO2 的提取率可达 93% 以上，镍、铁和镁等元素富集于渣中，氧化镍的质量含量达到 2.92%。 关键词：红土镍矿；熔融碱；二氧化硅 中图分类号：TD 982 ；TF 111.313 ；O 613.72 文献标识码：A Extraction of silicon from laterite-nickel ore by molten alkali MU Wen-ning, ZHAI Yu-chun, LIU Yan (School of Materials and Metallurgy, Northeastern University, Shenyang 110004, China) Abstract: The effects of reaction temperature, reaction time, mass ratio of alkali to ore, and agitation speed on the extracting ratio of SiO2 during the process of extracting silicon from laterite-nickel ore by molten alkali were investigated through orthogonal experiments. The results show that the sequence of each factor affecting the extracting ratio of SiO2 is reaction temperature ＞reaction time ＞mass ratio of alkali to ore ＞agitation speed. The optimum technological conditions are obtained as reaction temperature of 550 ℃, reaction time of 20 min, mass ratio of alkali to ore of 4׃1 and agitation speed of 400 r/min. The extracting ratio of SiO2 is over 93% under the optimum conditions, the elements of iron, magnesium and nickel are enriched in the residue, and the mass content of NiO is as high