单组分阴离子水性聚氨酯胶膜的热质研究-深圳大学.PDFVIP

37 8 Vo.l 37 No. 8 2007 8 PA INT COAT INGS INDUSTRY Aug. 2007 1 1 1 2 2 吕维忠, 刘 波 , 刘剑洪 , 涂伟萍 , 陈焕钦 ( 1. 深圳大学化学与化工学院, 广东深圳 518060, 2. 华南理工大学能源与化工学院, 广州510640) : (TG), : n( NCO) n( OH) , ; , ; DEG DEG /TMP ; TDI IPDI : ; ; ; ; : TQ 6307 : A : 0253- 4312( 2007) 07- 0009- 04 Study on Therm alProperty of One ComponentAnionicW aterborne Polyurethane by Therm ogravim etricM ethod 1 1 1 2 2 vW eizhong, iu Bo , iu Jianghong, TuWeiping , ChenHuanqin ( 1. College of Chemistry and ChiemicalEngineering, Shenzhen University, Shenzhen, Guangzhou 518060, China; 2. The School of Chem ical and Energy Engineering, South China University of Technology, Guangzhou 510640, China) Abstract: Therm al property of one component anionic waterborne polyurethane was studied by thermo gravmi etric(TG) method. The results show that therm al property of the coatings film will be enhanced w ith the increasing of NCO/ OH and reduced w ith the increasing of molecular weight of polyester. Therm al property of the film prepared by DEG as chain extender is better than that by DEG /TMP. Themalproperty of the film prepared by TD I is better than that by IPDI. K ey Words: waterborne polyurethane; anion; one component; thermogravmi etry; thermal property 0 . TDI, ; , , - ; DMPA, ; TMP, ; EDA, , [ 1- 2] ; BDO, ; DEG, ; NM P, [ 3] (T ) () g . 2 ()