第期王闳毅,等(Mg1–xYx)2Al4Si5O18陶瓷的相组成与微波介电性能.docVIP

低介电常数(Mg1–xYx)2Al4Si5O18陶瓷的制备与微波介电性能 王闳毅，刘 鹏，魏金生，吴 松，宋开新 (杭州电子科技大学电子信息学院，电子材料与器件重点实验室，杭州310018) 摘 要: 采用传统陶瓷固相反应烧结法制备(Mg1–xYx)2Al4Si5O18陶瓷。Y3+掺杂产生液相烧结作用，使得堇青石陶瓷的烧结温度从1 450 ℃降低到1 325 ℃。结果表明：(Mg1–xYx)2Al4Si5O18陶瓷在0≤x＜0.05的范围内以(Mg,Y)2Al4Si5O18固溶体形式存在在0.05≤x＜0.25的范围内以Mg2Al4Si5O18/Y2Si2O7复相陶瓷形式存在。Y3+能够改善(Mg1–xYx)2Al4Si5O18陶瓷的颗粒尺寸分布，并使陶瓷的气孔率得到降低。(Mg1–xYx)2Al4Si5O18陶瓷的相对介电常数由x=0的6.15提高到x=0.05的6.31；然后逐渐降低至x=0.25的5.90。品质因数Qf值由x = 0的33 000 GHz提高到x = 0.05的41 000 GHz，然后降低至x=0.25的24 000 GHz。谐振频率温度系数(0.05≤x＜0.25)值从–32×10–6/℃提高到–24×10–6/℃。 关键词: 堇青石；低介电常数；微波介电性能 中图分类号: TM221 文献标码: A 文章编号: 0454-5648(2015)XX-XXXX-XX 网络出版时间: DOI: 网络出版地址: Preparation and Microwave Dielectric Properties of (Mg1–xYx)2Al4Si5O18 Ceramics with Low Dielectric Constants WANG Hongyi，LIU Peng，WEI Jinsheng，WU Song，SONG Kaixin (College of Electronic Information and Engineering, Hangzhou DianZi University, Hangzhou 310018, China) Abstract: The (Mg1–xYx)2Al4Si5O18 ceramics were fabricated by a conventional solid phase sintering method. The sintering temperature decreases from 1 450 to 1 325 ℃ due to the effect of Y3+ doping producing liquid phase sintering. The X-ray powder diffraction patterns indicate that in the range of 0≤x＜0.05, (Mg1–xYx)2Al4Si5O18 ceramics consist of (Mg,Y)2Al4Si5O18 solid solution; and in the range of 0.05≤x＜0.25, (Mg1–xYx)2Al4Si5O18 ceramics exist in the form of both Mg2Al4Si5O18 and Y2Si2O7 composite phases. The results by scanning electron microscopy demonstrate that Y3+ doping reduces the porosity of (Mg1–xYx)2Al4Si5O18 ceramics and improves the particle size distribution of Mg2Al4Si5O18/Y2Si2O7 composite ceramics. The dielectric constants of (Mg1–xYx)2Al4Si5O18 ceramics firstly increase from 6.15 when x=0 to 6.31 when x=0.05, and then decrease to 5.90 when x=0.25. The quality factors (Qf values) of (Mg1–xYx)2Al4Si5O18 ceramics firstly increase from 33 000 GHz when x= 0 to 41 000 GHz when x=0.05, and then decrease to 24 000 GHz when x=0.25. The temperature coefficien