蒸发过程早期渗滤液中有机酸挥发规律研究.pdfVIP

第 28 卷第 4 期 环 　　境 　　科 　　学 Vol. 28 ,No. 4 2007 年 4 月 ENVIRONMENTAL SCIENCE Apr. ,2007 蒸发过程早期渗滤液中有机酸挥发规律研究 岳东北 ,许玉东 ,诸毅 ,苗豪梅 ,聂永丰 (清华大学环境科学与工程系 ,北京 　100084) ( 摘要 :对早期填埋场渗滤液进行了常规和载气蒸发实验 ,通过定时分批截留冷凝液并测定其 TOC 和挥发性脂肪酸 volatile fatty ) acids , VFAs 浓度 ,研究了不同 pH 条件下早期渗滤液中有机污染物的挥发规律. 结果表明 ,pH = 4 时蒸发冷凝液中 TOC 呈由高 ( ) 而低的变化趋势 ,pH = 7 时 TOC 变化趋势截然相反. 冷凝液中 VFAs 乙酸除外 浓度变化规律与 TOC 相似 ,并且结构越复杂相 对挥发速率越大. 分析表明 ,早期渗滤液蒸发冷凝液中有机物主要由 VFAs 组成. 是否具有载气及载气量多少对早期渗滤液有 机物蒸发的影响不明显. 关键词 :填埋场渗滤液 ;蒸发 ;冷凝液 ;挥发性脂肪酸 ( ) 中图分类号:X705 　文献标识码 :A 　文章编号 2007 Vaporization of Organic Acids from Young Landfill Leachate During Evaporation YUE Dongbei , XU Yudong , ZHU Yi , MIAO Haomei , NIE Yongfeng ( ) Department of Environmental Science and Engineering , Tsinghua University , Beijing 100084 , China Abstract :To obtain the vaporization rule of organic pollutants in a young landfill leachate , we conducted normal evaporation and gascarrying evaporation experiments , analyzing TOC and volatile fatty acids (VFAs) of batch condensate. The results showed that TOC in condensates declined when pH was 4 , whereas it presented a contrary trend when pH was 7. Variation of VFAs except acetic acid in condensates was similar to that of TOC. The more complicated the chemical construction of VFAs was , the greater the relative rate of vaporization was. The results indicated that the organic matter in c