大气污染控制Lecture 11-1 Control of Sulfur Oxides.pptVIP

Air Pollution Lecture 11 Control of Sulfur Oxides Lecture 11 Control of Sulfur Oxides Lecture 11 Control of Sulfur Oxides Ⅰ Harmful effects of Sulfur Oxides Ⅱ Sources of sulfur pollution Sources of sulfur pollution Ⅲ Removal of Reduced Sulfur compound (H2S) from Petroleum and Natural Gas Stream Ⅲ Removal of Reduced Sulfur compound (H2S) from Petroleum and Natural Gas Stream Ⅳ Removal of SO2 from the Rich Waste Gases Economic Problem Ⅴ Removal of SO2 from Lean Waste Gases (1) Problems of SO2 Removal by river water The first SO2 Removal process with river water (2) SO2 Removal by NaOH Solution (3) Forced-Oxidation Limestone Wet Scrubbers FGD 清华大学精品课程 (3) Forced-Oxidation Limestone Wet Scrubbers (4) Other SO2 Removal Processes 清华大学精品课程 清华大学精品课程 Ⅵ Alternatives to Sulfur Control Summary 清华大学大气污染控制工程精品课程网站 This Lecture and the Next Lecture Exerciser DISCUSSION * Particulate pollutants Volatile Organic Compounds (VOCs) Sulfur Oxides Nitrogen Oxides The four major air pollutants Particulate pollutants Volatile Organic Compounds (VOCs) Cyclone, ESP, filter, leakage control, vapor capture, condensation Mostly Physical process Sulfur Oxides Nitrogen Oxides Mostly chemical process Ⅰ Harmful effects of Sulfur Oxides Ⅱ Sources of sulfur pollution Ⅲ Removal of Reduced Sulfur compound (H2S) from Petroleum and Natural Gas Stream Ⅳ Removal of SO2 from the Rich Waste Gases Ⅴ Removal of SO2 from Lean Waste Gases Ⅵ Alternatives to Sulfur Control Strong respiratory irritants Secondary Particles and impairing visibility, PM10, PM2.5 Acid rain, Acid deposition Reduction Elemental form Oxidation First step Oxidation Second step Reaction with water Reaction with NH4+ or other cations N2 NO NO2 HNO3 NH3 Nitrate particles S SO2 SO3 H2SO4 H2S sulfate particles H2S Petroleum and natural gas streams SO2 Rich Waste Gases Copper, lead, zinc, and nickel smelters SO2 Lean Waste Gases Coal-burning electric power plant H2SO4 sulfate particles Secondary Particles S、CaSO4 harmless Feed