纳米增韧Φ100mm圆柱形NiFe2O4基惰性阳极的电解腐蚀行为研究.PDFVIP

Metallurgical Engineering 冶金工程, 2015, 2, 1-7 Published Online March 2015 in Hans. /journal/meng /10.12677/meng.2015.21001 Study on Electrolytic Corrosion Behavior and Mechanism of Nano Toughened Φ100 mm Cylindrical NiFe2O4 Based Inert Anode Zhigang Zhang, Jianrong Xu, Hongjie Luo, Guangchun Yao School of Materials Metallurgy, Northeastern University, Shenyang Liaoning Email: zhangzg@ th th rd Received: Feb. 10 , 2015; accepted: Feb. 24 , 2015; published: Mar. 3 , 2015 Copyright © 2015 by authors and Hans Publishers Inc. This work is licensed under the Creative Commons Attribution International License (CC BY). /licenses/by/4.0/ Abstract Nano toughened Φ100 mm cylindrical NiFe O based inert anodes was prepared by powder me- 2 4 tallurgy two-step sintering method. The electrolytic corrosion behavior and mechanism of NiFe2O4 based inert anodes were investigated by 10 h electrolysis experiment. The results show that the cell voltage keeps relatively stable, which is attributed to the good high temperature stability of nano toughened cylindrical NiFe2O4 based inert anode as well as the adequate high-temperature strength and conductivity of the solid state sintered connection between metal rod and inert anode. The electrolyzed inert anode has not undergone cracking or swelling, showing a suitable thermal shock resistance and corrosion resistance. The corrosion resistance should be enhanced for the purity of product aluminum was 98.02%, where the main impurities were Fe, Ni and Cu. The enhanced grain boundary bonding strength and decreased porosity, derived from the adding of Ni