自然铜炮制前后红外光谱、X 射线衍射和热重-差热 ... - 天津中草药杂志社.PDFVIP

中草药 Chinese Traditional and Herbal Drugs 第 42 卷 第 2 期 2011 年 2 月 • 275 • 自然铜炮制前后红外光谱、X 射线衍射和热重-差热分析 * 雷 雨，李伟东 ，李俊松，王洪斌，蔡宝昌 南京中医药大学 江苏省中药炮制重点实验室 国家中医药管理局中药炮制标准重点实验室，江苏 南京 210029 摘 要：目的 建立了全面分析鉴别自然铜生、煅品的方法。方法 利用远红外光谱分析、X 射线衍射、热重-差热分析对 自然铜生、煅品的结构组成、主要化学成分和热稳定性进行定性半定量分析。结果 远红外图谱分析显示：煅品有 Fe2O3 生成。X 射线衍射分析表明：生品主要物相为 FeS ，煅品出现了Fe S 、FeO(OH) 、Fe O 、Fe O 等复杂物相。热分析显示： 2 7 8 2 3 3 4 自然铜在400～1 000 ℃时，FeS2 逐渐分解；煅品成分结构变化较少。结论 以上分析方法鉴别自然铜生、煅品是可行的。 关键词：自然铜；生品；煅品；远红外光谱；X 射线衍射；热重-差热分析 中图分类号：R284.2 ；R286.02 文献标志码：A 文章编号：0253 - 2670(2011)02 - 0275 - 04 Far-infrared spectroscopy, X-ray diffraction, and thermogravimetric different thermal analyses on crude and processed Pyritum LEI Yu, LI Wei-dong, LI Jun-song, WANG Hong-bin, CAI Bao-chang Jiangsu Key Laboratory of Chinese Medicine Processing, State Key Laboratory of Standardization for Chinese Medicine Processing, State Administration of Traditional Chinese Medicines, Nanjing University of Chinese Medicine, Nanjing 210029, China Abstract: Objective To establish a method by which the multi-analysis and identification on the crude and processed Pyritum (natural coppor) could be carried out. Methods The qualitative and semi-quantitative analyses of the structure, chemical composition, and thermal stability of crude and processed Pyritum were determined by means of far-infrared (FIR) spectroscopy, X-ray diffraction (XRD) analyses, and thermogravimetric differential thermal analysis (TG-DTA). Results FIR spectroscopy showed that processed Pyritum had the chemical composition of Fe O . XRD analysis indicated that in crude Pyritum,