武汉秋冬季大气中TSPPM10浓度及其含金属的形态分布.docVIP

大气悬浮颗粒物中重金属含量和形态分析 吴桂萍,黄 富,韩 进,汪金晶,崔君涛,陈 伟,谢 达 (中南民族大学 化学与材料科学学院，催化材料科学国家民委-教育部共建重点实验室，武汉 430074) 摘 要 对某市大学校园内教学区、生活区和校外交通干道3个采样点秋冬季的大气颗粒物(TSP和PM10)浓度和颗粒物中的重金属元素Cu、Zn、Pb和Cr的浓度和形态分布进行了研究分析.结果表明：不同区域的TSP和PM10浓度差别较大，其中教学区最高，校外交通干道次之，生活区最低.TSP和PM10中Cu和Cr的含量较低，Zn和Pb的含量较高. TSP中重金属的总含量大于PM10，但是PM10中重金属所占的百分比大于TSP.从形态分布来看，TSP中Zn有40.76%存在于残渣态 (S5)中，PM10中Zn有53.43%存在于可交换态(S1).而TSP和PM10中Cu在前4态中分布较多，Pb主要存在于残渣态(S5)中，Cr的主要存在形态是氧化物结合态(S3)和残渣态(S5) .对TSP和PM10中重金属的生物有效性评价可知，Cu的可生物利用态含量最高，Zn、Pb和Cr的可生物利用态含量较低. 关键词 悬浮颗粒物；重金属；生物有效性 中图分类号 X831 文献标识码 A 文章编号 1672-4321(2014)01- Research on Contents and Speciation Analysis of Heavy Metals on Atmospheric Particles Wu Guiping, Huang Fu, Han Jin, Wang　Jinjing, Cui Juntao, Chen Wei, Xie Da (Key Laboratory for Catalysis and Material Science of State Ethnic Affairs Commission - Ministry of Education,College of Chemistry and Material Science, South-Central University for Nationalities, Wuhan,430074, China) Abstracts :S amples of TSP and PM10 were collected in the teaching area, living area of university campus and main road out of campus in one city in autumn and winter to study and evaluate the concentration of TSP and PM10 and the speciations, pollution level and bioavailability of Cu , Zn ,Pb and Cr in the atmospheric particles. The results showed that the concentration of TSP and PM10 are obviously different in different areas, among which the teaching area is the highest, followed by campus roads, and living area is the minimum.The content of Cr and Cu were low in TSP and PM10, whereas the content of Zn and Pbwere high. The total content of heavy metals in TSP is higher than in PM10,but the relative content of heavy metals in PM10 is higher than TSP. From the percentage distribution of species, approximately 40.76% of Zn existed in the residue state (S5) in TSP, and about 53.43% of Zn presented in exchangeable state (S1). Cu mainly appeared in the previous 4 state distributions, and Pb mainly appeared in the residue