热处理对高岭石结构转变及活性的影响.pdfVIP

第 22 卷第 1 期 中国有色金属学报 2012 年 1 月 Vol.22 No.1 The Chinese Journal of Nonferrous Metals Jan. 2012 文章编号：1004-0609(2012)1-0258-07 热处理对高岭石结构转变及活性的影响 匡敬忠，邱廷省，施 芳 (江西理工大学 资源与环境工程学院，赣州 341000) 摘 要：采用煅烧高岭石的方法制备矿物聚合材料，采用 DTA−TG 、XRD 和 IR 分析等手段研究高岭石经过热处 理后的结构转变过程。结果表明：热处理直接影响到高岭石结构转变及煅烧高岭石的活性。煅烧后，高岭石的结 构转变经历了脱羟基(约 541 ℃) 、偏高岭石化(541～850 ℃)和 Al2O3 分凝(＞950 ℃)3 个过程，煅烧温度达到 950 ℃ 后，生成新相 γ-Al O 。通过对煅烧高岭石所制备的矿物聚合材料抗折强度的评价确定了煅烧高岭石活性较适宜的 2 3 热处理制度：煅烧温度为 850 ℃，煅烧时间 3 h。煅烧高岭石的长程无序特征是煅烧高岭石具有较高活性的原因， γ-Al2O3 的生成是导致煅烧高岭石活性下降和矿物聚合材料抗折强度降低的主要原因。 关键词：高岭石；煅烧；活性；结构转变；矿物聚合材料 中图分类号：TQ177 文献标志码：A Effect of heat treatment on structure transformation and activities of kaolinite KUANG Jing-zhong, QIU Ting-sheng, SHI Fang (Faculty of Resource and Environmental Engineering, Jiangxi University of Science and Technology, Ganzhou 341000, China) Abstract: The geopolymers were prepared by calcining kaolinite. The structure transformation for calcined kaolinite was studied by means of differential thermal analysis-thermal gravity, X-ray diffraction and infrared. The results show that heat treatment directly affects the structure transformation of kaolinite and activity of calcination kaolinite. The structure transformation for calcined kaolinite is undergone some stages including kaolinite dehydroxylation (about 541 ℃), metakaolinite formation (541−850 ℃) and Al O segregation ( ＞950 ℃). The new phase formed at 950 ℃ is γ-Al O .