- 1、本文档共49页,可阅读全部内容。
- 2、原创力文档(book118)网站文档一经付费(服务费),不意味着购买了该文档的版权,仅供个人/单位学习、研究之用,不得用于商业用途,未经授权,严禁复制、发行、汇编、翻译或者网络传播等,侵权必究。
- 3、本站所有内容均由合作方或网友上传,本站不对文档的完整性、权威性及其观点立场正确性做任何保证或承诺!文档内容仅供研究参考,付费前请自行鉴别。如您付费,意味着您自己接受本站规则且自行承担风险,本站不退款、不进行额外附加服务;查看《如何避免下载的几个坑》。如果您已付费下载过本站文档,您可以点击 这里二次下载。
- 4、如文档侵犯商业秘密、侵犯著作权、侵犯人身权等,请点击“版权申诉”(推荐),也可以打举报电话:400-050-0827(电话支持时间:9:00-18:30)。
查看更多
有机化学Chap
axial bond: the set of six, straight up and down bonds in chair cyclohexane. Ring flip interconverts these bonds with the set of equatorial bonds. equatorial bond: the set of six, also “up and down”, but more or less in the plane of the ring in chair cyclo-hexane. These bonds are interconverted with the set of axial bonds through ring “flipping” of the chair. Summary: Substituted Cyclohexane Compounds In a sample of cyclohexane, the two identical chair conformers are present in equal concentration, and the hydrogens are all equivalent (50% equatorial 50% axial) due to rapid interconversion of the conformers. When the cyclohexane ring bears a substituent, the two chair conformers are not the same. In one conformer the substituent is axial, in the other it is equatorial. Due to steric hindrance in the axial location, substituent groups prefer to be equatorial and that chair conformer predominates in the equilibrium. Chair conformations are generally more stable than other possibilities. * Substituents 取代on chair conformers prefer to occupy equatorial positions due to the increased steric hindrance of axial locations. * The following equations and formulas illustrate how the presence of two or more substituents on a cyclohexane ring perturbs the interconversion of the two chair conformers in ways that can be predicted. We noted earlier that cycloalkanes having two or more
substituents on different ring carbon atoms exist as a
pair (sometimes more) of configurational stereoisomers.
Now we must examine the way in which favorable ring
conformations influence the properties of the configu-
rational isomers.
Remember, configurational stereoisomers are stable and do not easily interconvert, whereas, conformational
isomers normally interconvert rapidly. In examining
possible structures for substituted cyclohexanes, it is
useful to follow two principles.
? Conformational Structures of Disubstituted Cyclohexanes 1,1-dimethylcyc
您可能关注的文档
- 最新官方QS2015世界大学排名.docx
- 最新小学六年级信息技术上册教案(贵州科技出版社)1.doc
- 最新人教版七下英语uint6.ppt
- 最新外研版英语九年级下册Module5-Unit-1.ppt
- 最新人教版八下英语课件Unit2.ppt
- 最新外研版英语九年级下册Module6_Unit_1.ppt
- 最新外研版九上M2U1.ppt
- 最新人教版英语八年级上册Unit5Do you want to watch a game show.ppt
- 最新外研版初二下册Module4 Unit2课件.ppt
- 最新招商银行招聘笔试面试全套复习资料历年完整真题机考系统手机app题库.doc
- 《JJF 2132-2024荧光紫外灯人工气候老化试验装置校准规范:辐射照度参数》.pdf
- JJF 2120-2024轮速传感器校准规范.pdf
- 计量规程规范 JJF 2120-2024轮速传感器校准规范.pdf
- 《JJF 2129-2024钙钛矿太阳电池校准规范:光电性能参数》.pdf
- JJF 2129-2024钙钛矿太阳电池校准规范:光电性能参数.pdf
- 《JJF 2120-2024轮速传感器校准规范》.pdf
- JJF 2117-2024沥青混合料理论最大相对密度仪校准规范.pdf
- JJF 2116-2024特定蛋白分析仪校准规范.pdf
- 《JJF 2116-2024特定蛋白分析仪校准规范》.pdf
- 计量规程规范 JJF 2117-2024沥青混合料理论最大相对密度仪校准规范.pdf
文档评论(0)