浙江大学化学系有机合成化学OS7-1.pptVIP

Electrophilic Carbon-Carbon Bond Forming Reactions Carbocations Selective cation rearrangement Friedel-Crafts reactions. Formation of heteroatom-containing derivatives ?-allyl palladium complexes Carbocations Cation stability Cationic rearrangements Carbocation reactions with alkene nucleophiles Cation stability Cationic rearrangements Example Example Carbocation reactions with alkene nucleophiles Example Selective cation rearrangement The Pinacol rearrangement Koch-Haaf carbonylation Nazarov cyclization The Prins reaction The Pinacol rearrangement Koch-Haaf carbonylation Nazarov cyclization The Prins reaction Friedel-Crafts reactions. Formation of heteroatom-containing derivatives Synthesis of quinoline derivatives Synthesis of isoquinoline derivatives The Fischer indole synthesis Synthesis of acridines,carbazoles, and phenanthridines Synthesis of oxygenerated aromatic derivatives Synthesis of quinoline derivatives Example Synthesis of isoquinoline derivatives Example The Fischer indole synthesis Example Synthesis of acridines,carbazoles, and phenanthridines Synthesis of oxygenerated aromatic derivatives Example ?-allyl palladium complexes Formation of ?-allyl palladium complexes Reaction of ?-allyl palladium complexes Catalytic ?-allyl palladium reactions Paladium coupling reactions Formation of ?-allyl palladium complexes Reaction of ?-allyl palladium complexes Catalytic ?-allyl palladium reactions Example Example Paladium coupling reactions The Heck reaction Stille coupling Suzuki coupling Sonogashira and Stephen-Castro coupling The Heck reaction Example Stille coupling Suzuki coupling Sonogashira and Stephen-Castro coupling * Knorr quinoline synthesis Gould-Jacobs reaction Combes quinoline synthesis Doebner-Miller reaction Skraup reaction Bischler-Napieralski reaction Pictet-Spengler isoquinoline synthesis acridine carbazole phenanthridine *