第六章 分子的结构与性质-合肥工业大学-无机化学.pdf

6.1 6.1 6.2 6.2 6.3 6.3 6.4 MO 6.4 MO 6.5 6.5 6.1.1 298⋅15K HCl (g) H(g) + Cl(g) E (H-Cl)= H =431kJ·mol-1 =(D) 298⋅15K H2 (g) 2H(g) E (H-H)= =436kJ·mol-1 , = H O(g) H(g) + OH(g) 2 D (H-OH) = 498 kJ·mol-1 OH(g) H(g) + O(g) D (O-H) = 428 kJ·mol-1 E (O-H)=½{D (H-OH)+D (O-H)}=463kJ·mol-1 N O (g) D (N-N) = 167 kJ·mol-1 2 4 N H (g) D (N-N) = 247 kJ·mol-1 2 4 6.1. 2 (L ) 6.1. 2 (L ) b b H H Cl Cl Br Br I I H F H Cl H Br H I L /pm 74.0 198.8 228.4 266.6 91.8 127.4 140.8 160.8 b C-C L /pm 154 153 154 155 b C C C=C C C N N N = N N N C N C=N C N L /pm 154 134 120 146 125 109.8 147 116 b 6.1.3 6.1.3 V 6.2.1 6.2.1