以桐油为基质自由基聚合型UV涂料之合成与应用-国立中兴大学实验.DOC

桐油為基質自由基聚合型UV塗料之合成與應用 盧崑宗1 吳幸芳2 【摘要】本研究係將桐油先與甘油行酯交換反應形成甘油酯後，再異氰酸酯與甲基丙烯酸2-羥乙基酯反應合成壓克力胺酯，對全量樹脂液重量3%之光引發劑 (Irgacure 651)調配成自由基聚合型之UV塗料甲基丙烯酸甲酯二丙烯酸1,6-己二醇酯三羥甲醇丙烷三丙烯酸酯單體對塗料與塗膜性質之影響。試驗結果發現，桐油與甘油之酯交換反應溫度設定為190℃時，才可穩定地得到甘油酯壓克力胺酯需5 h甘油酯，才能使反應自由基型UV塗料塗膜且富含光澤，其中又以反應性單體為TMPTA者，塗膜性質較為均衡，但應用於木材塗料上，其塗膜與耐久性仍需進一步加以改善。壓克力胺酯1.國立中興大學森林系副教授，台中市402國光路250號，通訊作者。 Associate Professor, Department of Forestry, National Chung Hsing University. 250 Kuo-Kung Rd. 402, Taichung, Taiwan. Corresponding Author. 2.國立中興大學森林系碩士。 Master, Department of Forestry, National Chung Hsing University. Synthesis and Applications of Tung Oil-based Free Radical Polymerization UV coatings Kun-Tsung Lu1 Hsing-Fang Wu2 【Abstract】 oil-based acrylated urethane oilgomers for free radical polymerization UV coatings were synthesized by reacting glyceride with polyiscyanate (PTDI) and 2-Hydroxyethyl methacrylate (HEMA). The glycerides were obtained by transesterification of tung oil and glycerin. The UV coating formulations were based on the weight ratio of oligomer/monomer of 80/20, and in conjunction with 3% photoinitiator (Irgacure 651) by the weight ratio of total resins. The effect of the functionality of monomers such as mono-functional methyl methacrylate (MMA), di-functional 1,6-hexanediol diacrylate (HDDA), and tri-functional trimethylolpropane triacrylate (TMPTA) on the properties of UV coatings and its feasibility for wood finishing were examined. The results indicated that the adequate temperature was at 190℃ for transesterification reaction, and the reaction time of glyceride for preparing acrylated urethane oilgomers was at least 5 h and the glyceride should slowly be added to the reactant mixture drop by drop. The UV coatings had an excellent curing behavior, and superior mechanical properties and gloss of film. Among the UV coatings, the one containing TMPTA had the best hardness, tensile strength, and a balance effect on the properties of coating and films. However, the poor adhesion and durability of this