甲醇制烯技术简介.ppt

A Brief Introduction to methanol to Olefins Technology甲醇制烯烃技术简介 Background; BP experience; Economics; Status 工业背景;BP公司工业化经验;经济性和应用情况 甲醇制烯烃技术平台Methanol to Olefins – the technology platform The starting point is methanol which can be produced from a number of feedstocks eg gas, oil, coal and biomass through gasification to syngas as feedstock for methanol. 该工艺技术是以天然气、石油、煤和生物燃料通过气化反应制取含有甲醇的合成气体作为原料。 Olefins, predominantly ethylene and propylene can be produced with a selective catalyst from methanol. Two process variants have been developed (a) eg UOP and DICP to produce ethylene and propylene mixtures (MTO) and (b) Lurgi/EXXON to produce essentially propylene and pygasoline (MTP). They differ in the catalyst and process conditions. 使用选择性催化剂，可用甲醇制取烯烃，主要是乙烯和丙烯。目前有两种工艺已得到发展：(a)UOP和DICP生产乙烯和丙烯混合物的技术（MTO）；(b)鲁奇/埃克森生产丙烯和重质热解汽油技术（MTP）。这两种工艺使用的催化剂和工艺条件不同。 Both variants are readily integrated into existing naphtha steam crackers due to low paraffin make. 由于链烷烃含量低，两种工艺可以容易地移植到现有的石脑油蒸汽裂化装置上。 DICP and partners have recently demonstrated their MTO development at ca 10,000tpa. DICP公司及其合作伙伴最近在加拿大一个加工量为10,000tpa装置上示范了其MTO技术的发展。 Pilot plant 15kg/hr methanol Statoil; C3= into PP and liquids to gasoline – RON OK BP公司评述与评估BP Reviews and Assessments Throughout 2000-2003 BP carried out a number of assessments of methanol to olefins technology for gas ideal sites like bpTT. These were led in conjunction with our olefins BU (Chemicals). 在2000-2003年，BP公司为bpTT这样拥有理想气体的公司进行了数次甲醇制烯烃技术评估。而且都是与我们的烯烃BU（化学）公司一起进行评估的。 This period of activity was characterised by relatively low oil prices and large scale methanol (mega-methanol) plants were not yet constructed eg ATLAS 5000tpd. 这一时期的活动有着油价相对低的特点.大型甲醇工厂（百万吨甲醇) 没能建设起来。例如：ATLAS工厂，其生产能力为 5000tpd。 There is much internal work documented in the bpTT team and many studies carried out within BP which we can draw on for comparative economics and more detailed understanding. bpTT 团队对大量内部工作进行了论证,BP内部完成了许多研究，由于其比较经济学和资料详尽,我们可以利用这些研究。 UOP的MTO工艺 与 Lurgi的 MTP工