BAM蓝粉荧光粉热劣化现象研究现状.pdf

34 2 江 苏 冶 金 Vol. 34 No. 2 2006 4 Jiangsu Metallurgy Apr . 2006 BAM 吴直森, 刘凯, 梁步青, 吴竞, 曹同, 董岩, 蒋建清 ( , 210096) : PDP BaMgA 110O17: Eu2+ ( BAM) BAM , BAM , BAM : BAM; ; :T N1415 ( ) AlMg O , 32 , ( PDP) ACBA , 64 [ 1~ 4] , PDP 32 ( Y, Gd) BO3 : Eu3+ ( Y, Gd) 2 O3 : , 24 3+ 2+ 2+ 3+ 3+ 3+ Eu BaAl12 O19 : Mn Zn2 SiO4 : Mn Ba Al , A l , 16 Al 2+ [ 5, 6] 2+ MgAl10 O17 : Eu BaMgAl10 O17 : Eu , ( BAM) ( Eu2+ ) , , ( VU V) , , PDP , , , , , BAM PDP , , , [ 12~ 15] [ 7~ 10] BAM BAM BAM , BAM BAM , BAM 1 BAM 1 BAM Al O 2 3 10 17 BA M BAM BaMgA l O Al2 O3 , NaA l11 O17 , Eu2+ , Eu2+ [ 11] 2+ 1 A l2 O3 Ba Eu , 7 2 2+ 4f 6s , Eu Eu , : : ( 197 ) , , : ( 025) 36 9556 2 , : BAM 5 7 [ 23] 4f 147 nm 172 nm , 1 100 , Eu2+ , 4f 5d EuMgA l11 O19 BAM , 5d 4f , 450 nm , , BAM 2+ Eu 4f 5d , 600~ 700 , , 4f 5d Eu2+ 5d , ,