红白、黄白双色微胶囊电泳显示器件的制备研究.pdfVIP

摘 要 本文研究制备了红白、黄白双色微胶囊电泳显示器件。研究了改性的颜料红 254 、颜料黄13 和颜料黄181 的电泳显示液配方；优化了一步原位聚合法制备脲 醛树脂微胶囊的制备工艺；探索了刮刀式涂布法制备微胶囊涂膜的工艺。 采用正交实验系统研究了电泳显示液的配方，考察了T-151、CTAB、CH-5 和Span85 对电泳显示液的电泳淌度和分散粒径的影响，确定了三种电泳液的优 化配方；采用三种电泳液分别与白色电泳液进行复配制得双色电泳液，将双色电 泳液灌封于微杯显示器件中，得到的器件的对比度值分别是1.65，1.22 和1.28。 采用一步原位聚合法制备包裹双色电泳液的脲醛树脂微胶囊，以微胶囊的形 貌为依据，考察了壁材与芯材质量比、交联剂的用量、反应pH 值等条件对制备 的微胶囊的影响，通过优化工艺制备的微胶囊粒径均匀、表面光滑、机械强度高， 胶囊粒径分布在40~100 μm之间，平均粒径为75 μm，囊壁厚度在300 nm 以上， 同时胶囊内的粒子在15 V/mm 的电场下可实现电泳响应。 采用刮刀式涂布法探索微胶囊涂膜的制备工艺，考察了胶合剂、涂布厚度和 干燥方式等对涂膜的表面形貌及制备的微胶囊显示器件显示性能的影响，制备出 了一种红白双色，两种黄色双色的微胶囊电泳显示原型器件。器件的对比度值分 别为1.85，1.19 和1.23。 关键词： 微胶囊电泳显示，原位聚合法，脲醛树脂，彩色电泳粒子，涂布 ABSTRACT A series of dual colored microcapsule type electrophoretic display (EPD) prototypes were prepared and studied in this paper. The main research contents including: study on the formulation of electrophoretic suspensions contained C. I. Pigment Red 254 (PR254), C. I. Pigment Yellow 13 (PY13) and C. I. Pigment Yellow 181 (PY181), respectively; the preparation of urea-formaldehyde microcapsules contained dual-colored electrophoretic suspensions via in situ polymerization; study on the coating process and preparation of microcapsule type EPD prototypes. The formulations of electrophoretic suspensions were investigated by orthogonal experiment method. Influence factor of concentration of T-151, CTAB, Span85 and CH-5 on the suspension properties were discussed. The microcup EPDs were fabricated by filling the dual-colored electrophoretic suspensions into a 7-section display prototype. The contrast ratio of these displays is 1.65, 1.22 and 1.28, respectively. Functional microcapsules were prepared via in situ polymerization. This paper d