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65聚合条件对PEDT导电性及相对分子质量的影响-本原扫描探针
26 10 Vol.26 No.10
2007 10 ELECTRONIC COMPONENTS AND MATERIALS Oct. 2007
PEDT
1 2
3, 4-PEDT
1 490%0.5%
–5 20 S/cm
25 =14 2
PEDT 1 068 7.6
PEDT ;
TN604 A 100110-0021-04
n
Influence of synthesis conditions on the electrical conductivity
c
.
and relative molecular mass of PEDT
m
1 2
XIONG Ping XU Jian-hua
o
1.Chengdu Electronicmechanic CollegeChengdu 610031China 2.University of Electronic Science and Technology
Chengdu 610054China
c
.
Abstract: Conducting poly(34-ethylene dioxythiophene) film was prepared by in situ chemical oxidation method. The
influences of different process factors on the film electric conductivity were investigated. The results show that the higher
m
conductivity film ( 20 S/cm) can be obtained through following polymerization conditions: an 14 volume ratio of
monomer to oxidizer, 90% volume fraction of solvent, 0.5% volume fraction of accelerant, and –5 of polymerization
p
temperature. Furthermore, with the a
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