北京市海淀区大气PM10中正构烷烃的分布研究.pdfVIP

第15卷 第6期 安徽建筑工业学院学报(自然科学版) Vo1．15 NO．6 2007年 12月 Journal of Anhui Instituteof Architecture Industry Dec．2007 北京市海淀区大气PMI O中正构烷烃的分布研究 杜 娟 (安徽建筑工业学院环境工程系，合肥 230022) 摘 要：利用索氏抽提与层析柱前处理以及气相色谱／质谱联用技术(GC—MS)等方法检测了2004～2005年 北京市海淀区采样点大气PMIO中的正构烷烃。实验数据表明，正构烷烃的碳数分布范围在nC ～nC。z之 间，相对含量较大的范围为nC ～nCz。，且随碳数递增，正构烷烃以等间距顺序出峰，秋季和夏季的色谱图基 线比较平稳，UCM鼓包峰较小，冬季有不明显的UCM鼓包峰，春季有明显的UCM鼓包峰，23≤Cmax~27，1 CPI3，(nC +nC )／(nC 。+nC 。)值除冬季以外，春季、夏季和秋季的平均值均小于1。表明北京市海淀 区2004~2005年大气PMIO中均检测出丰富的正构烷烃，正构烷烃主要来自高等植物等现代生物和化石燃 料(石油、煤等)的不完全燃烧双重来源。 关键词：PMIO；正构烷烃；气相色谱／质谱联用；来源分析 中图分类号：X131 文献标识码：A 文章编号：1006—4540(2o07)06-032—06 Distribution Research of n—alkanes in PM 1 0 on Haidian Districtin Beijing DU Juan (Dept of Environmental Engineering，Anhui University of Architecture，He~el 230022，China) Abstract：N-alkanes from the PMIO in Northwest urban District of Beijing during 2004 and 2005 were analyzed by Soxhlet extraction、chromatography column pre—treatment and GC—MS technique methods． It indicates by experimental data that the carbon number ranging from nCll to nC32 increases progres— sively with the carbon number，the larger range of relative content is between nC16 to nC29，n—alkanes peaks sequence is equal space，the chromatogram charts in autumn and summer are comparatively sta— ble，the UCM bulge is comparatively small that is not obvious in winter and obvious in spring，23≤ Cmax27，1CPI3，the average values of(nC21+nC22)／(nC28+nC29)are allless than 1 in addition to winter．these show that n-alkanes 0f PM10 in the northwest 0f Beijing City from 2004 to 2005 were mainly from modern biology such as higher plants and incomplete combustion of fossil fuels(oil、coa1)． Key words：PM10；n-alkanes；GC—MS；source analysis 污染物向大气中的排放使得人类直接暴露在 中的重要组成部分口]，