甘油催化氢解制备二元醇的研究进展.pdfVIP

Dec. 2010 现代化工 30 12 16 M odern Chem ica l Indu stry 2010 12 甘油催化氢解制备二元醇的研究进展 1 1 1 2 3 2 岳桂淑 , 吴红军, 王宝辉 , 董 晶 , 李 超, 田春雨 ( 1. 东北石油大学化学化工学院, 黑龙江大庆 163318; 2. 大庆油田有限责任公司, 黑龙江大庆 163453; 3. 中国石油大港石化公司, 天津 300280 : , , , : ; ; 1, 2-; 1, 3-; ; : O 64332; TQ 203. 2 : A : 0253- 4320( 20 10 12- 00 16 - 05 Study on catalytic hydrogenoly sis of glycerol to d iols 1 1 1 2 3 2 YUE Guishu , W U H ong j un , WAN G Baohu i, DON G J ing , LI Chao , TIAN Ch unyu ( 1. College of Chem istry and Chem ica l Eng ineer ing, No rtheast Petro leum U n iversity, D aqing 163318, China; 2. D aq ing O ilf ield Co. , L td. , D aqing 163453, China; 3. P etroCh ina D agang P etrochem ica l Company, T ianj in 300280, China A b stract: R ecent advances in cata ly tic hydrogeno ly sis o f g lycero l to diols a re review ed. The reaction m echanism and the production techno logy o f ca talytic hydrog enolysis of g lycerol to dio ls are in troduced. The progress of cata ly sts u sed in cata ly tic hydrogeno lys is of g lycero l to d io ls is emphasized. F ina lly, som e sugg estions are provided fo r the resea rch direction of cata lytic hydrogeno lys is of g ly cero l to dio ls. K ey w ords: glycero l; cata lytic hydrogeno lysis; 1, 2propaned io l; 1, 3propanedio;l ethy lene g lyco;l cata ly st ( 1, 2- 1, 3- , 3-, , 1, 2- 1, 3- 10 t/ a, 6 t/ a, 4 t [ 5- 1